Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses,Structures, Magnetic, and Luminescent Properties
文献类型：期刊论文
| 作者 | Li, Wu
|
| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2012 |
| 卷号 | 638期号:11页码:1833-1838 |
| 关键词 | Aryl-oxide ligand In situ metal ligand reaction Coordination |
| ISSN号 | 0044-2313 |
| 英文摘要 | The reaction of the aryl-oxide ligand H2L [H2L = N,N-bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine] with CuSO4 center dot 5H2O, CuCl2 center dot 2H2O, CuBr2, CdCl2 center dot 2.5H2O, and Cd(OAc)2 center dot 2H2O, respectively, under hydrothermal conditions gave the complexes [Cu(H2L1)2]center dot SO4 center dot 3CH3OH (1), [Cu2(H2L2)2Cl4] (2), [Cu2(H2L2)2Br4] (3), [Cd2(HL)2Cl2] (4), and [Cd2(L)2(CH3COOH)2]center dot H2L (5), where H2L1 [H2L1 = 2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl)phenol] and H2L2 [H2L2 = 2-(2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl)phenoxy)-4, 6-dimethylphenol] were derived from the solvothermal in situ metal/ligand reactions. These complexes were characterized by IR spectroscopy, elementary analysis, and X-ray diffraction. A low-temperature magnetic susceptibility measurement for the solid sample of 2 revealed antiferromagnetic interactions between two central copper(II) atoms. The emission property studies for complexes 4 and 5 indicated strong luminescence emission. The reaction of the aryl-oxide ligand H2L [H2L = N,N-bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine] with CuSO4 center dot 5H2O, CuCl2 center dot 2H2O, CuBr2, CdCl2 center dot 2.5H2O, and Cd(OAc)2 center dot 2H2O, respectively, under hydrothermal conditions gave the complexes [Cu(H2L1)2]center dot SO4 center dot 3CH3OH (1), [Cu2(H2L2)2Cl4] (2), [Cu2(H2L2)2Br4] (3), [Cd2(HL)2Cl2] (4), and [Cd2(L)2(CH3COOH)2]center dot H2L (5), where H2L1 [H2L1 = 2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl)phenol] and H2L2 [H2L2 = 2-(2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl)phenoxy)-4, 6-dimethylphenol] were derived from the solvothermal in situ metal/ligand reactions. These complexes were characterized by IR spectroscopy, elementary analysis, and X-ray diffraction. A low-temperature magnetic susceptibility measurement for the solid sample of 2 revealed antiferromagnetic interactions between two central copper(II) atoms. The emission property studies for complexes 4 and 5 indicated strong luminescence emission. |
| 收录类别 | SCI |
| 公开日期 | 2013-09-22 |
| 源URL | [http://ir.isl.ac.cn/handle/363002/2029]  |
| 专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
| 推荐引用方式 GB/T 7714 | Li, Wu. Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses,Structures, Magnetic, and Luminescent Properties[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2012,638(11):1833-1838. |
| APA | Li, Wu.(2012).Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses,Structures, Magnetic, and Luminescent Properties.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,638(11),1833-1838. |
| MLA | Li, Wu."Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3,5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses,Structures, Magnetic, and Luminescent Properties".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 638.11(2012):1833-1838. |
入库方式： OAI收割
来源：青海盐湖研究所
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