中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of uniform titanium dioxide (TiO2) polystyrene-based composite particles using the glass membrane emulsification process with a subsequent suspension

文献类型:期刊论文

作者Supsakulchai, A (Supsakulchai, A) ; Ma, GH (Ma, GH) ; Nagai, M (Nagai, M) ; Omi, S (Omi, S)
刊名JOURNAL OF MICROENCAPSULATION
出版日期2003
卷号20期号:1页码:1-18
关键词titanium dioxide polystyrene copolymer photo-oxidation catalyst suspension polymerization microcasule microparticle
英文摘要Uniform titanium dioxide (TiO2)-polystyrene-based composite particles were prepared using the glass membrane emulsification process followed by a subsequent suspension polymerization. The oil phase, consisting of anatase TiO2 ne powder, monomers, methyl laurate as the hydrophobic additive, Disperbyk-180 and the poly(styrene-co-2-ethyl hexylacrylate) were emulsified through the membrane pores into the aqueous phase containing stabilizers to form a (solid-in-oil)-in-water (S/O/W) emulsion of monomer droplets. The suspension polymerization was carried out at 343 K for 24 h under a nitrogen atmosphere. An SPG membrane with a pore size of 5.25 mum was employed and 20-25 mum TiO2-polystyrene based composite particles were obtained depending on the composition of polymerizing oil phase. The effects of the co-monomer, 2-ethylhexyl acrylate and the cross-linking agent, divinyl benzene on the dispersion stability of TiO2 in the oil phase, the surface feature of the particle and the encapsulation loading were investigated in this study. The membrane emulsification process was capable of preparing the composite particles with similar to5 wt% of TiO2 encapsulated, which accounts for with at least 85 wt% of TiO2 in the oil phase.
收录类别SCI
语种英语
公开日期2013-09-20
版本出版稿
源URL[http://ir.ipe.ac.cn/handle/122111/1572]  
专题过程工程研究所_生化工程国家重点实验室
推荐引用方式
GB/T 7714
Supsakulchai, A ,Ma, GH ,Nagai, M ,et al. Preparation of uniform titanium dioxide (TiO2) polystyrene-based composite particles using the glass membrane emulsification process with a subsequent suspension[J]. JOURNAL OF MICROENCAPSULATION,2003,20(1):1-18.
APA Supsakulchai, A ,Ma, GH ,Nagai, M ,&Omi, S .(2003).Preparation of uniform titanium dioxide (TiO2) polystyrene-based composite particles using the glass membrane emulsification process with a subsequent suspension.JOURNAL OF MICROENCAPSULATION,20(1),1-18.
MLA Supsakulchai, A ,et al."Preparation of uniform titanium dioxide (TiO2) polystyrene-based composite particles using the glass membrane emulsification process with a subsequent suspension".JOURNAL OF MICROENCAPSULATION 20.1(2003):1-18.

入库方式: OAI收割

来源:过程工程研究所

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