Selectivity-tunable oxidation of tetrahydro-beta-carboline over an OMS-2 composite catalyst: preparation and catalytic performance
文献类型：期刊论文
| 作者 | Bi, Xiuru1,2; Tao, Luyao1,2; Yao, Nan2; Gou, Mingxia2 ; Chen, Gexin2; Meng, Xu2; Zhao, Peiqing2
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| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2021-03-14 |
| 卷号 | 50期号:10页码:3682-3692 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/d1dt00168j |
| 通讯作者 | Meng, Xu(xumeng@licp.cas.cn) ; Zhao, Peiqing(zhaopq@licp.cas.cn) |
| 英文摘要 | Controlling the reaction selectivity of organic transformations without losing high conversion is always a challenge in catalytic processes. In this work, a H3PO4 center dot 12WO(3)/OMS-2 nanocomposite catalyst ([PW]-OMS-2) was prepared through the oxidation of a Mn(ii) salt with sodium phosphotungstate by KMnO4. Comprehensive characterization indicates that different Mn2+ precursors significantly affected the crystalline phase and morphology of the as-synthesized catalysts and only MnSO4 center dot H2O as the precursor could lead to a cryptomelane phase. Moreover, [PW]-OMS-2 demonstrated excellent catalytic activity toward aerobic oxidative dehydrogenation of tetrahydro-beta-carbolines due to mixed crystalline phases, enhanced surface areas, rich surface oxygen vacancies and labile lattice oxygen species. In particular, beta-carbolines and 3,4-dihydro-beta-carbolines could be obtained from tetrahydro-beta-carbolines with very high selectivity (up to 99%) over [PW]-OMS-2 via tuning the reaction solvent and temperature. Under the present catalytic system, scalable synthesis of a beta-carboline was achieved and the composite catalyst showed good stability and recyclability. This work not only clarified the structure-activity relationship of the catalyst, but also provided a practical pathway to achieve flexible, controllable synthesis of functional N-heterocycles. |
| 资助项目 | National Natural Science Foundation of China[21403256] ; National Natural Science Foundation of China[21573261] ; Youth Innovation Promotion Association CAS[2018456] ; LICP Cooperation Foundation for Young Scholars[HZJJ20-10] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; LICP Cooperation Foundation for Young Scholars |
| 源URL | [http://ir.licp.cn/handle/362003/28454]  |
| 专题 | 中国科学院兰州化学物理研究所 |
| 通讯作者 | Meng, Xu; Zhao, Peiqing |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bi, Xiuru,Tao, Luyao,Yao, Nan,et al. Selectivity-tunable oxidation of tetrahydro-beta-carboline over an OMS-2 composite catalyst: preparation and catalytic performance[J]. DALTON TRANSACTIONS,2021,50(10):3682-3692. |
| APA | Bi, Xiuru.,Tao, Luyao.,Yao, Nan.,Gou, Mingxia.,Chen, Gexin.,...&Zhao, Peiqing.(2021).Selectivity-tunable oxidation of tetrahydro-beta-carboline over an OMS-2 composite catalyst: preparation and catalytic performance.DALTON TRANSACTIONS,50(10),3682-3692. |
| MLA | Bi, Xiuru,et al."Selectivity-tunable oxidation of tetrahydro-beta-carboline over an OMS-2 composite catalyst: preparation and catalytic performance".DALTON TRANSACTIONS 50.10(2021):3682-3692. |
入库方式： OAI收割
来源：兰州化学物理研究所
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