中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 兰州化学物理研究所
  3. 中国科学院兰州化学物理研究所
  4. OSSO国家重点实验室
Grignard-Reagent-Promoted Desulfonylation/Intramolecular Coupling for the Synthesis of 2-(1-Fluorovinyl)pyridines

文献类型：期刊论文

作者Kang, Lei1,2; Zhang, Jinlong2; Yang, Huameng2; Qian, Jinlong2; Jiang, Gaoxi2
刊名ORGANIC LETTERS
出版日期2020-11-20
卷号22期号:22页码:9118-9122
ISSN号1523-7060
DOI10.1021/acs.orglett.0c03521
通讯作者Qian, Jinlong(q124802q@163.com) ; Jiang, Gaoxi(gxjiang@licp.cas.cn)
英文摘要A novel process involving Grignard-reagent-promoted desulfonylation/intramolecular coupling of readily available alpha-fluoro-alpha,beta-unsaturated-(2-pyridyl)sulfones was realized that provided a series of polysubstituted 2-(1-fluorovinyl)pyridines in good yields. The intrinsic coordination between pyridine and Mg(II) along with the "negative fluorine effect" of the substrates should play the key role for the smooth transformation in the absence of transition-metal catalysts.
资助项目National Natural Science Foundation of China[21602231] ; Chinese Academy of Sciences Light of West China Program ; Natural Science Foundation of Jiangsu Province[BK20160396] ; Natural Science Foundation of Jiangsu Province[BK20191197]
WOS研究方向Chemistry
语种英语
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; Chinese Academy of Sciences Light of West China Program ; Natural Science Foundation of Jiangsu Province
源URL[http://ir.licp.cn/handle/362003/28239]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Qian, Jinlong; Jiang, Gaoxi
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Ctr Excellence Mol Synth, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat,Lanzhou I, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714		 Kang, Lei,Zhang, Jinlong,Yang, Huameng,et al. Grignard-Reagent-Promoted Desulfonylation/Intramolecular Coupling for the Synthesis of 2-(1-Fluorovinyl)pyridines[J]. ORGANIC LETTERS,2020,22(22):9118-9122.
APA Kang, Lei,Zhang, Jinlong,Yang, Huameng,Qian, Jinlong,&Jiang, Gaoxi.(2020).Grignard-Reagent-Promoted Desulfonylation/Intramolecular Coupling for the Synthesis of 2-(1-Fluorovinyl)pyridines.ORGANIC LETTERS,22(22),9118-9122.
MLA Kang, Lei,et al."Grignard-Reagent-Promoted Desulfonylation/Intramolecular Coupling for the Synthesis of 2-(1-Fluorovinyl)pyridines".ORGANIC LETTERS 22.22(2020):9118-9122.

入库方式： OAI收割

来源：兰州化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。