Measurement of Specific Heat Capacity of NaBO2 (aq) Solution and Thermodynamic Modeling of NaBO2 + H2O, NaBO2 + NaCl + H2O, and NaBO2 + Na2SO4 + H2O Systems
文献类型：期刊论文
| 作者 | Ye, Liuying; Li, Dongdong ; Dong, Ya-Ping; Xu, Baoming; Zeng, Dewen
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| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
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| 出版日期 | 2020-05-14 |
| 卷号 | 65期号:5页码:2548-2557 |
| ISSN号 | 0021-9568 |
| DOI | 10.1021/acs.jced.9b01182 |
| 英文摘要 | The specific heat capacity of NaBO2(aq) solution was determined using a Calvet-type calorimeter at a temperature from 288.15 to 338.15 K and at a concentration from about 0.25 mol.k(-1) H2O to near room temperature solubility limit. Combining these specific heat capacity data and thermodynamic and solid-liquid equilibrium data reported in the literature, a temperature-dependent thermodynamic model was developed for the NaBO2 + H2O system based on Pitzer-Simonson-Clegg activity coefficient equations. The model represents all of the properties over a wide temperature and concentration ranges. Combining the binary models of NaCl + H2O and Na2SO4 + H2O systems published in the previous studies of our group, multitemperature thermodynamic models of the NaBO2 + NaCl + H2O and NaBO2 + Na2SO4 + H2O systems were constructed. These ternary models reproduce the experimental solubility isotherms reported in the literature in general, but some significant inconsistency is still present. More accurate solubility data for these ternary systems at various temperatures are urgent. |
| 源URL | [http://ir.isl.ac.cn/handle/363002/33898]  |
| 专题 | 中国科学院青海盐湖研究所 青海盐湖研究所_盐湖资源与化学实验室 |
| 推荐引用方式 GB/T 7714 | Ye, Liuying,Li, Dongdong,Dong, Ya-Ping,et al. Measurement of Specific Heat Capacity of NaBO2 (aq) Solution and Thermodynamic Modeling of NaBO2 + H2O, NaBO2 + NaCl + H2O, and NaBO2 + Na2SO4 + H2O Systems[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2020,65(5):2548-2557. |
| APA | Ye, Liuying,Li, Dongdong,Dong, Ya-Ping,Xu, Baoming,&Zeng, Dewen.(2020).Measurement of Specific Heat Capacity of NaBO2 (aq) Solution and Thermodynamic Modeling of NaBO2 + H2O, NaBO2 + NaCl + H2O, and NaBO2 + Na2SO4 + H2O Systems.JOURNAL OF CHEMICAL AND ENGINEERING DATA,65(5),2548-2557. |
| MLA | Ye, Liuying,et al."Measurement of Specific Heat Capacity of NaBO2 (aq) Solution and Thermodynamic Modeling of NaBO2 + H2O, NaBO2 + NaCl + H2O, and NaBO2 + Na2SO4 + H2O Systems".JOURNAL OF CHEMICAL AND ENGINEERING DATA 65.5(2020):2548-2557. |
入库方式： OAI收割
来源：青海盐湖研究所
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