中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Phase Equilibrium in Aqueous Systems Containing Magnesium Borate

文献类型:期刊论文

作者Ge, Haiwen; Wang, Min; Zhou, Yongquan; Deng, Tianlong; Yao, Yan
刊名RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
出版日期2019-08
卷号93期号:8页码:1478-1483
ISSN号0036-0244
DOI10.1134/S0036024419080090
英文摘要The phase equilibria in the aqueous system containing magnesium borate at 0, 25, and 50 degrees C was studied using isothermal dissolution equilibrium method, and the solubilities, and acidity were determined. Detailed investigation of aqueous hungchaoite solutions has been performed by Raman spectroscopy at 25 degrees C. The results showed the phase transformation of hungchaoite has not appeared at 0 degrees C, the B( OH) and B( OH) 3 are dominant species and the concentration of polyborate remain constant. It was found that hungchaoite will transform into inderite ( Mg2B6O11 center dot 15H2O) in aqueous solution at 25 and 50 degrees C and the value of mB2O3/ mMgO has as clear ascendant trend after 240 and 10 h, respectively. The mole fractions of B( OH) 3 and B3O3( OH) are increasing, and the trend is opposite to B( OH) and B4O5( OH). According to the experimental result, the relevant chemical reaction and mechanism were suggested in the dissolution and transformation processes.
源URL[http://ir.isl.ac.cn/handle/363002/34104]  
专题青海盐湖研究所_盐湖资源与化学实验室
中国科学院青海盐湖研究所
推荐引用方式
GB/T 7714
Ge, Haiwen,Wang, Min,Zhou, Yongquan,et al. Phase Equilibrium in Aqueous Systems Containing Magnesium Borate[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2019,93(8):1478-1483.
APA Ge, Haiwen,Wang, Min,Zhou, Yongquan,Deng, Tianlong,&Yao, Yan.(2019).Phase Equilibrium in Aqueous Systems Containing Magnesium Borate.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,93(8),1478-1483.
MLA Ge, Haiwen,et al."Phase Equilibrium in Aqueous Systems Containing Magnesium Borate".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 93.8(2019):1478-1483.

入库方式: OAI收割

来源:青海盐湖研究所

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