中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Lithium isotope separation by crown ethers of different nitrogen-containing derivatives in the ionic liquid-anisole system

文献类型:期刊论文

作者Liu, Bing; Wang, Su; Jia, Yongzhong; Zhu, Wenbo; Zhang, Quanyou; Wang, Xingquan; Yao, Ying; Jing, Yan
刊名JOURNAL OF MOLECULAR LIQUIDS
出版日期2018-12-15
卷号272页码:548-553
ISSN号0167-7322
DOI10.1016/j.molliq.2018.09.105
英文摘要A green and efficient ionic liquid-anisole extraction system was employed for the separation of lithium isotopes by comparing 4-aminobenzo-15-crown-5 (4-NH2-B15C5), 4-nitrobenzo-15-crown-5 (4-NO2-B15C5) and benzo-15-crown-5 (B15C5) extraction agents. The results of the effects of crown ether substituents, crown ether concentration and lithium salt anion on solvent extraction indicated that the molar ratio of crown ether and lithium ion complex is 2:1 and the order of the extraction efficiency in three extraction agents was 4-NH2-B15C5 > B15C5 > 4-NO2-B15C5. Furthermore, the single-stage separation factor a for Li-6/Li-7 obtained in present work was 1.032 and maximum abundance of Li-6 in organic phase was reached 7.762% in the extraction system of LiI/4-NO2-B15C5-ILs. (C) 2018 Elsevier B.V. All rights reserved.
源URL[http://ir.isl.ac.cn/handle/363002/34457]  
专题青海盐湖研究所_盐湖资源综合利用工程技术中心
推荐引用方式
GB/T 7714
Liu, Bing,Wang, Su,Jia, Yongzhong,et al. Lithium isotope separation by crown ethers of different nitrogen-containing derivatives in the ionic liquid-anisole system[J]. JOURNAL OF MOLECULAR LIQUIDS,2018,272:548-553.
APA Liu, Bing.,Wang, Su.,Jia, Yongzhong.,Zhu, Wenbo.,Zhang, Quanyou.,...&Jing, Yan.(2018).Lithium isotope separation by crown ethers of different nitrogen-containing derivatives in the ionic liquid-anisole system.JOURNAL OF MOLECULAR LIQUIDS,272,548-553.
MLA Liu, Bing,et al."Lithium isotope separation by crown ethers of different nitrogen-containing derivatives in the ionic liquid-anisole system".JOURNAL OF MOLECULAR LIQUIDS 272(2018):548-553.

入库方式: OAI收割

来源:青海盐湖研究所

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