Lithium isotopes separation by using benzo-15-crown-5 in eco-friendly extraction system
文献类型：期刊论文
| 作者 | Xiao, Jiang; Jia, Yongzhong ; Shi, Chenglong; Wang, Xingquan; Wang, Su; Yao, Ying; Jing, Yan
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| 刊名 | JOURNAL OF MOLECULAR LIQUIDS
 |
| 出版日期 | 2017-09 |
| 卷号 | 241页码:946-951 |
| ISSN号 | 0167-7322 |
| DOI | 10.1016/j.molliq.2017.06.119 |
| 英文摘要 | A green and efficient liquid-liquid extraction system was developed for the separation of lithium isotopes by using hydrophobic ionic liquids (ILs = [C(4,6,8.10)mini](+)[NTf2](-)) as extraction organic phase and benzo-15crown-5 (B15C5) as complexing agent. The maximum single-stage separation factor alpha of Li-6/Li-7 obtained in this study was 1.029 +/- 0.001, indicating Li-6 was enriched in ionic liquid phase while Li-7 was concentrated in the aqueous phase. The lithium ion was extracted into the ionic liquid in the formation of 1:2 complex [Li+(B15C5)(2)]. The negative data of thermodynamic parameters (Delta H-0 and Delta G(0)) suggest that the extraction system was a spontaneous exothermic process. In addition, effective lithium isotopes separation factor and the extraction efficiency of lithium ions can be gained in the condition of lower temperature with softer counter anions in the novel extraction system. (C) 2017 Elsevier B.V. All rights reserved. |
| 源URL | [http://ir.isl.ac.cn/handle/363002/34564]  |
| 专题 | 青海盐湖研究所_盐湖资源综合利用工程技术中心 |
| 推荐引用方式 GB/T 7714 | Xiao, Jiang,Jia, Yongzhong,Shi, Chenglong,et al. Lithium isotopes separation by using benzo-15-crown-5 in eco-friendly extraction system[J]. JOURNAL OF MOLECULAR LIQUIDS,2017,241:946-951. |
| APA | Xiao, Jiang.,Jia, Yongzhong.,Shi, Chenglong.,Wang, Xingquan.,Wang, Su.,...&Jing, Yan.(2017).Lithium isotopes separation by using benzo-15-crown-5 in eco-friendly extraction system.JOURNAL OF MOLECULAR LIQUIDS,241,946-951. |
| MLA | Xiao, Jiang,et al."Lithium isotopes separation by using benzo-15-crown-5 in eco-friendly extraction system".JOURNAL OF MOLECULAR LIQUIDS 241(2017):946-951. |
入库方式： OAI收割
来源：青海盐湖研究所
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