中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Design and facile one-step synthesis of FeWO4 Fe2O3 di-modified WO3 with super high photocatalytic activity toward degradation of quasi-phenothiazine dyes

文献类型:期刊论文

作者Wang, Huixiang; Wang, Conghui; Cui, Xinmin; Qin, Li; Ding, Ruimin; Wang, Liancheng; Liu, Zhong; Zheng, Zhanfeng; Lv, Baoliang
刊名APPLIED CATALYSIS B-ENVIRONMENTAL
出版日期2018-02
卷号221页码:169-178
ISSN号0926-3373
DOI10.1016/j.apcatb.2017.09.011
英文摘要For most of WO3, a visible-light-driven photocatalyst, its barrier in photocatalytic degradation is the low conduction band (CB) potential that can not reduce O-2 to O-2(-) center dot and HO2 center dot radicals and thus results in fast recombination of electron/hole. With this in mind, a new active FeWO4/Fe2O3 di-modified WO3 was designed and prepared via by a straightforward but effective strategy by introducing of FeWO4 and Fe2O3 clusters (or nanoparticles) on WO3. The performance of di-modified WO3 showed super high photocatalytic activity in degrading quasi-phenothiazine dyes of Methylene blue (MB), Toluidine blue (TB), Azure I (AI) and Acridine orange (AO) under visible light irradiation, and the corresponding k values are 5.3, 4.4, 3.8 and 5.8 times larger than that of pure WO3, respectively. This improvement was mainly due to the fact that photoexcited electrons can migrate to the matching CB of firmly and highly dispersed FeWO4 and Fe2O3, then be consumed rapidly by a valence decrease from Fe3+ to Fe2+ and Fenton reaction between Fe2+ and H2O2. And the strong adsorption of Fe species toward N and S (or N) elements in quasi-phenothiazine dyes, also positively promoted the efficiency of degradation.
源URL[http://ir.isl.ac.cn/handle/363002/34464]  
专题青海盐湖研究所_盐湖资源与化学实验室
推荐引用方式
GB/T 7714
Wang, Huixiang,Wang, Conghui,Cui, Xinmin,et al. Design and facile one-step synthesis of FeWO4 Fe2O3 di-modified WO3 with super high photocatalytic activity toward degradation of quasi-phenothiazine dyes[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2018,221:169-178.
APA Wang, Huixiang.,Wang, Conghui.,Cui, Xinmin.,Qin, Li.,Ding, Ruimin.,...&Lv, Baoliang.(2018).Design and facile one-step synthesis of FeWO4 Fe2O3 di-modified WO3 with super high photocatalytic activity toward degradation of quasi-phenothiazine dyes.APPLIED CATALYSIS B-ENVIRONMENTAL,221,169-178.
MLA Wang, Huixiang,et al."Design and facile one-step synthesis of FeWO4 Fe2O3 di-modified WO3 with super high photocatalytic activity toward degradation of quasi-phenothiazine dyes".APPLIED CATALYSIS B-ENVIRONMENTAL 221(2018):169-178.

入库方式: OAI收割

来源:青海盐湖研究所

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