Ultrasensitive dual-mode visualization of perchlorate in water, soil and air boosted by close and stable Pt-Pt packing endowed low-energy absorption and emission
文献类型:期刊论文
作者 | Su, Z (Su, Zhen) [1] , [2]; Li, YS (Li, Yushu) [1]; Li, JG (Li, Jiguang) [1] , [2]; Li, K (Li, Kun) [3]; Dou, XC (Dou, Xincun) [1] , [2] |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A |
出版日期 | 2022 |
卷号 | 10期号:15页码:8195-8207 |
ISSN号 | 2050-7488 |
DOI | 10.1039/d2ta00843b |
英文摘要 | The accurate, ultrasensitive and rapid onsite analysis of perchlorate either in water, soil or air is urgently needed for public security checking, explosive ordnance disposal, environment monitoring and forensic analysis. To achieve it, a Pt(ii) terpyridyl complex-based sensing platform that can realize the onsite ultrasensitive, colorimetric and luminescent dual-mode, rapid and direct detection of perchlorate in water, soil and air was successfully developed by systematic molecular design. The high-contrast color change from pale-yellow to purple-red and turn-on mode red luminescent emission can greatly eliminate environmental fluctuations and background autofluorescence, thus enabling the detection of perchlorate more accurately, discriminatively and efficiently even in a complex environment. The excellent water-solubility of the Pt(ii) terpyridyl complex and the introduction of the hydrogel matrix largely enhance the sensing capacity and achieve the direct ultrasensitive detection of perchlorate microparticulates in soil or air, with a limit of detection of 0.45 ng by naked eye and 0.02 fg by common optical microscope. The present study provides a valuable strategy for designing a Pt(ii) complex-based sensor with high-contrast color change, high signal-to-noise ratio luminescence, and ultrasensitive detection ability for particulate analytes, which would shine light on the design of high-performance sensing platforms for various analytes. |
WOS记录号 | WOS:000774051000001 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/8361] |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_环境科学与技术研究室 |
通讯作者 | Li, YS (Li, Yushu) [1]; Dou, XC (Dou, Xincun) [1] , [2] |
作者单位 | 1.Taiyuan Univ Sci & Technol, Sch Mat Sci & Engn, Shanxi Key Lab Met Forming Theory & Technol, Taiyuan 030024, Peoples R China 2.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Explos Safety Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Su, Z ,Li, YS ,Li, JG ,et al. Ultrasensitive dual-mode visualization of perchlorate in water, soil and air boosted by close and stable Pt-Pt packing endowed low-energy absorption and emission[J]. JOURNAL OF MATERIALS CHEMISTRY A,2022,10(15):8195-8207. |
APA | Su, Z ,Li, YS ,Li, JG ,Li, K ,&Dou, XC .(2022).Ultrasensitive dual-mode visualization of perchlorate in water, soil and air boosted by close and stable Pt-Pt packing endowed low-energy absorption and emission.JOURNAL OF MATERIALS CHEMISTRY A,10(15),8195-8207. |
MLA | Su, Z ,et al."Ultrasensitive dual-mode visualization of perchlorate in water, soil and air boosted by close and stable Pt-Pt packing endowed low-energy absorption and emission".JOURNAL OF MATERIALS CHEMISTRY A 10.15(2022):8195-8207. |
入库方式: OAI收割
来源:新疆理化技术研究所
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