Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation
文献类型：期刊论文
| 作者 | Zheng,Yu ; Yang,Hong-Dou; Wei,Kun; Yang,Yu-Rong
|
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2021 |
| 卷号 | 86期号:8页码:6025-6029 |
| 关键词 | ENANTIOSELECTIVE TOTAL-SYNTHESIS ALPHA-ALLYLATION STEMONA ALKALOIDS IRIDIUM |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.1c00390 |
| 英文摘要 | The common, key tricyclic core of stemona alkaloids parvistemonine (1) and parvistemoline (2), whose synthetic efforts have not reported yet, was constructed through a new strategy in which three contiguous stereogenic centers were set by using Carreira's asymmetric Ir/amine-catalyzed allylation of aldehyde with alpha-vinylfurfuryl alcohol and Ellman's sulfinamide chiral auxiliary, respectively. The furan ring was especially designed to act as the precursor of the butyrolactone while establishing the significant chirality. |
| WOS记录号 | WOS:000641292800054 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/73224]  |
| 专题 | 中国科学院昆明植物研究所 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Yang, Hong-Dou 3.Wei, Kun 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.[Zheng, Yu |
| 推荐引用方式 GB/T 7714 | Zheng,Yu,Yang,Hong-Dou,Wei,Kun,et al. Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation[J]. JOURNAL OF ORGANIC CHEMISTRY,2021,86(8):6025-6029. |
| APA | Zheng,Yu,Yang,Hong-Dou,Wei,Kun,&Yang,Yu-Rong.(2021).Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation.JOURNAL OF ORGANIC CHEMISTRY,86(8),6025-6029. |
| MLA | Zheng,Yu,et al."Synthetic Studies toward Parvistemoline Using Asymmetric Ir/Amine-Catalyzed Allylation".JOURNAL OF ORGANIC CHEMISTRY 86.8(2021):6025-6029. |
入库方式： OAI收割
来源：昆明植物研究所
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