Total Synthesis of Dysifragilones A and B and Dysidavarone C
文献类型：期刊论文
| 作者 | Li,Yang-Ming; Sun,Yu-Tong; Li,Bi-Yuan; Qin,Hong-Bo
|
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2021 |
| 卷号 | 23期号:18页码:7254-7258 |
| 关键词 | NO PRODUCTION SESQUITERPENE ANALOGS ROUTE |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.1c02641 |
| 英文摘要 | The concise synthesis of dysifragilones A and B and dysidavarones has been accomplished for the first time in a divergent way from a common intermediate. The synthetic route features an intramolecular reductive Heck reaction to construct the 6/5/6/6/-tetracycle of dysifragilones A and B and an intramolecular palladium-catalyzed alpha-arylation of a sterically hindered ketone to forge the tetracyclo[7.7.1.0(2,7).0(10,15)]heptadecane core structure of dysidavarone C. The late-stage introduction of amino and ethoxy groups is effective. |
| WOS记录号 | WOS:000697348600048 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/73351]  |
| 专题 | 中国科学院昆明植物研究所 |
| 作者单位 | 1.[Li, Yang-Ming 2.Yunnan Minzu Univ, Sch Chem & Environm, Kunming 650031, Yunnan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Yunnan Key Lab Nat Med Chem, Kunming 650201, Yunnan, Peoples R China 5.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 6.Li, Bi-Yuan 7.Sun, Yu-Tong |
| 推荐引用方式 GB/T 7714 | Li,Yang-Ming,Sun,Yu-Tong,Li,Bi-Yuan,et al. Total Synthesis of Dysifragilones A and B and Dysidavarone C[J]. ORGANIC LETTERS,2021,23(18):7254-7258. |
| APA | Li,Yang-Ming,Sun,Yu-Tong,Li,Bi-Yuan,&Qin,Hong-Bo.(2021).Total Synthesis of Dysifragilones A and B and Dysidavarone C.ORGANIC LETTERS,23(18),7254-7258. |
| MLA | Li,Yang-Ming,et al."Total Synthesis of Dysifragilones A and B and Dysidavarone C".ORGANIC LETTERS 23.18(2021):7254-7258. |
入库方式： OAI收割
来源：昆明植物研究所
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