中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Bisabolane, cadinane, and cyclonerane sesquiterpenes from an algicolous strain of Trichoderma asperelloides

文献类型:期刊论文

作者Zou,Ji-Xue; Song,Yin-Ping; Liu,Xiang-Hong; Li,Xiao-Nian; Ji,Nai-Yun
刊名BIOORGANIC CHEMISTRY
出版日期2021
卷号115页码:105223
关键词Trichoderma Sesquiterpene Bisabolane Cadinane Cyclonerane METABOLITES HARZIANE
ISSN号0045-2068
DOI10.1016/j.bioorg.2021.105223
英文摘要Ten new bisabolane derivatives, trichobisabolins Q-Z (1-10), one new cadinane derivative, cadin-4-en-11-ol (11), and three new cyclonerane derivatives, cycloner-3-en-7,11-diol (12), isoepicyclonerodiol oxide (13), and norepicyclonerodiol oxide (14), were isolated from the endophytic fungal strain RR-dl-6-11 of Trichoderma asperelloides that was obtained from a marine alga. Their structures along with relative configurations were established mainly by NMR and IR as well as MS techniques, and the absolute configurations of 10 and 11 were assigned by ECD and X-ray diffraction data, respectively. Sesquiterpenes from the fungus T. asperelloides are reported for the first time. It is interesting that half of the bisabolane derivatives are demethylated. Compound 12 represents the first the occurrence of cyclopentenyl-bearing cycloneranes, and 14 seems a cyclopentyl-degrading cyclonerane derivative. Several isolates feature potent inhibition of marine phytoplankton species.
WOS记录号WOS:000704133100007
源URL[http://ir.kib.ac.cn/handle/151853/73590]  
专题中国科学院昆明植物研究所
作者单位1.Chinese Acad Sci, Ctr Ocean Megasci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Kunming Inst Bot, Kunming 650201, Yunnan, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.[Zou, Ji-Xue
5.Song, Yin-Ping
6.Liu, Xiang-Hong
推荐引用方式
GB/T 7714
Zou,Ji-Xue,Song,Yin-Ping,Liu,Xiang-Hong,et al. Bisabolane, cadinane, and cyclonerane sesquiterpenes from an algicolous strain of Trichoderma asperelloides[J]. BIOORGANIC CHEMISTRY,2021,115:105223.
APA Zou,Ji-Xue,Song,Yin-Ping,Liu,Xiang-Hong,Li,Xiao-Nian,&Ji,Nai-Yun.(2021).Bisabolane, cadinane, and cyclonerane sesquiterpenes from an algicolous strain of Trichoderma asperelloides.BIOORGANIC CHEMISTRY,115,105223.
MLA Zou,Ji-Xue,et al."Bisabolane, cadinane, and cyclonerane sesquiterpenes from an algicolous strain of Trichoderma asperelloides".BIOORGANIC CHEMISTRY 115(2021):105223.

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来源:昆明植物研究所

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