Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural
文献类型：期刊论文
| 作者 | Hu, Zhi2,3; Xie, Aidi2; Chen, Chun2,3 ; Zou, Zidan2,3; Shen, Yue2,3; Fu, Zhen3; Zhang, Yunxia2,3; Zhang, Haimin2,3; Zhao, Huijun1,3; Wang, Guozhong2,3
|
| 刊名 | FUEL
 |
| 出版日期 | 2022-07-01 |
| 卷号 | 319 |
| 关键词 | N, P co-doped Ionic liquid Hydrogenation Rearrangement Nickel |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2022.123815 |
| 通讯作者 | Chen, Chun(chenchun2013@issp.ac.cn) ; Wang, Guozhong(gzhwang@issp.ac.cn) |
| 英文摘要 | Aqueous-phase hydrogenation-rearrangement tandem (AP-HRT) reaction is a green and sustainable route to produce cyclopentanone from bio-based furan compounds. Herein, the ionic liquid was applied as the precursor to synthesize Ni@NP-C catalyst, which contains high dispersed nickel nanoparticles (Ni NPs) encapsulated in the N, P co-doped carbon layer, for the selectivity transformation of furfural towards cyclopentanone. The synthesized Ni@NP-C catalyst can afford 100% FAL conversion and 86.7% CPO yield at 130 degrees C and 1.5 MPa H-2 within 2 h AP-HRT reaction. The introduction of the electronegative heteroatom on the surface can not only improve the adsorption of reactant but also provide weak Lewis Acid sites for being beneficial to the high selectivity of cyclopentanone. The catalyst displays superior activity, selectivity, and stability in the tandem catalytic system in view of the tunable chemical states of the doped heteroatoms by handily adjusting the pyrolysis temperature. |
| WOS关键词 | HYDROGENATIVE RING-REARRANGEMENT ; CHEMOSELECTIVE HYDROGENATION ; NANOPARTICLES ; CONVERSION ; EFFICIENT |
| 资助项目 | National Natural Science Foundation of China[51871209] ; National Natural Science Foundation of China[52072371] ; Key Technologies Research and Development Program of Anhui Province[202004a06020056] ; Special Foundation of President of HFIPS[YZJJ202102] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000783223300002 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Natural Science Foundation of China ; Key Technologies Research and Development Program of Anhui Province ; Special Foundation of President of HFIPS |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/128561]  |
| 专题 | 中国科学院合肥物质科学研究院 |
| 通讯作者 | Chen, Chun; Wang, Guozhong |
| 作者单位 | 1.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Brisbane, Qld 4222, Australia 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Ctr Environm & Energy Nanomat, Key Lab Mat Phys,HFIPS, Hefei 230031, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Zhi,Xie, Aidi,Chen, Chun,et al. Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural[J]. FUEL,2022,319. |
| APA | Hu, Zhi.,Xie, Aidi.,Chen, Chun.,Zou, Zidan.,Shen, Yue.,...&Wang, Guozhong.(2022).Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural.FUEL,319. |
| MLA | Hu, Zhi,et al."Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural".FUEL 319(2022). |
入库方式： OAI收割
来源：合肥物质科学研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。