UV curing polyurethane-acrylate composites as full filling thermal interface materials
文献类型:期刊论文
作者 | Che, Yamin2,3; Liu, Cui1,3; Li, Nian1,3; Guo, Wei2,3; Xi, Min1,3; Zhang, Shudong1,3; Wang, Zhenyang1,3 |
刊名 | NEW JOURNAL OF CHEMISTRY |
出版日期 | 2022-05-03 |
卷号 | 46 |
ISSN号 | 1144-0546 |
DOI | 10.1039/d2nj00397j |
通讯作者 | Zhang, Shudong() ; Wang, Zhenyang(zywang@iim.ac.cn) |
英文摘要 | Ideal thermal interface materials (TIMs) can completely fill the interfaces among components to enhance heat transfer between devices and they have emerged as a major strategy to solve heat dissipation problems. However, some micro-scale voids and cavities existing at a device interface can hardly be adequately filled by externally squeezing in the highly elastic thermal interface material, which badly hinders heat transfer. Therefore, the light curing method is a very good path to obtain pre-filled TIMs, which can adequately fill micro-scale voids and cavities and perfectly replicate textures from the interfaces of components. Herein, a kind of polyurethane acrylate (PUA) resin with UV curability and conformal contact flexibility was chosen as a matrix, and an added photoinitiator was excited by UV irradiation to produce active species to trigger polymerization of the active group in the liquid material, thus curing it. By adding copper nanowires (Cu NWs) to bridge the modified hBN, a three-dimensional (3D) heat transfer network is formed to improve the thermal conductivity of the PUA resin. The thermal conductivity of the hBN@PEI-Cu NWs/PUA composites can reach 1.535 W m(-1) K-1 at 20 wt% addition of total fillers. Meanwhile, the composites show excellent electrical insulation and good flexibility, and can be stretched, twisted and knotted arbitrarily when used directly, indicating their strong potential in practical applications. |
WOS关键词 | GRAPHITE NANOPLATELET ; EPOXY COMPOSITES ; CARBON NANOTUBE ; CONDUCTIVITY ; FILMS ; NANOCOMPOSITES ; ENHANCEMENT ; FILLER |
资助项目 | National Key Research and Development Project[2020YFA0210703] ; Special fund project for local science and technology development guided by the central government of Anhui Province[202107d08050016] ; Major Scientific and Technological Special Project of Anhui Province[202103a05020192] ; Technological Innovation Projects of Shandong Province[2019JZZY020243] ; National Natural Science Foundation of China[U2032159] ; National Natural Science Foundation of China[U2032158] ; National Natural Science Foundation of China[62005292] ; Major Scientific and the CASHIPS Director's Fund[YZJJZX202015] ; Collaborative Innovation Program of Hefei Science Center, CAS[2020HSC-CIP003] ; Key Research and Development Program of Anhui Province[202104a05020036] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000781252000001 |
资助机构 | National Key Research and Development Project ; Special fund project for local science and technology development guided by the central government of Anhui Province ; Major Scientific and Technological Special Project of Anhui Province ; Technological Innovation Projects of Shandong Province ; National Natural Science Foundation of China ; Major Scientific and the CASHIPS Director's Fund ; Collaborative Innovation Program of Hefei Science Center, CAS ; Key Research and Development Program of Anhui Province |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/128567] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Zhang, Shudong; Wang, Zhenyang |
作者单位 | 1.Chinese Acad Sci, Hefei Inst Phys Sci, Key Lab Photovolta & Energy Conservat Mat, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Che, Yamin,Liu, Cui,Li, Nian,et al. UV curing polyurethane-acrylate composites as full filling thermal interface materials[J]. NEW JOURNAL OF CHEMISTRY,2022,46. |
APA | Che, Yamin.,Liu, Cui.,Li, Nian.,Guo, Wei.,Xi, Min.,...&Wang, Zhenyang.(2022).UV curing polyurethane-acrylate composites as full filling thermal interface materials.NEW JOURNAL OF CHEMISTRY,46. |
MLA | Che, Yamin,et al."UV curing polyurethane-acrylate composites as full filling thermal interface materials".NEW JOURNAL OF CHEMISTRY 46(2022). |
入库方式: OAI收割
来源:合肥物质科学研究院
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