Magnetic properties and giant cryogenic magnetocaloric effect in B-site ordered antiferromagnetic Gd2MgTiO6 double perovskite oxide
文献类型：期刊论文
| 作者 | Zhang, Yikun2,3,4,5,6; Tian, Yun3,4,5; Zhang, Zhenqian2; Jia, Youshun2; Zhang, Bin3,4,5; Jiang, Minqiang1 ; Wang, Jiang3,4,5; Ren, Zhongming3,4,5; Jiang MQ(蒋敏强); Jiang MQ(蒋敏强)
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| 刊名 | ACTA MATERIALIA
 |
| 出版日期 | 2022-03-01 |
| 卷号 | 226页码:9 |
| ISSN号 | 1359-6454 |
| 关键词 | Magnetocaloric performances Magnetic phase transition Magnetocaloric (MC) effect Rare earths based double perovskite oxides |
| DOI | 10.1016/j.actamat.2022.117669 |
| 通讯作者 | Zhang, Yikun(ykzhang@shu.edu.cn) |
| 英文摘要 | The magnetic refrigeration (MR) technology by utilizing the magnetocaloric (MC) effects of magnetic solids have been realized to be a promising energy efficiency and environmentally friendly technology. Developing or discovering proper magnetic solids with promising MC performances is one of the most important tasks at present stage since a huge gap still exists between the requirement of practical MR application and the MC performances of the magnetic solids. Herein, we reported a combined theoretical and experimental investigation of the crystal structure together with the magnetic properties, magnetic phase transition (MPT) and MC performances in Gd2MgTiO6 oxide. The Gd2MgTiO6 is confirmed to crystalize in a B-site ordered monoclinic double perovskite (DP) crystal structure. A rather unstable anti ferromagnetic (AFM) interaction with large magnetic moment and semi-conductor characteristic with the band gap of 2.977 eV have been confirmed in Gd2MgTiO6 DP oxide at ground state. Giant reversible cryogenic MC effect together with excellent MC performances have been confirmed by a series of the figure of merits including the values of maximum magnetic entropy change (-delta S-M) and refrigerant capacity ( RC ), which are evaluated to be 46.21 J/kgK and 300.27 J/kg around 3.3 K with the magnetic change of 0-7 T, these values are much better than most of the recently reported famous cryogenic MC materials and the commercialized magnetic refrigerants gadolinium gallium garnet (GGG) as well. The observed excellent MC performances suggest that Gd2MgTiO6 DP oxide is a promising candidate material for cryogenic MR applications. (C)& nbsp;2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
| WOS关键词 | MAGNETIC-PROPERTIES ; ACHIEVEMENT ; REFRIGERATION ; PERFORMANCES |
| 资助项目 | National Natural Science Foundation of China[52071197] ; Pioneer and Leading Goose R&D Program of Zhejiang[2022C01230] ; Science and Technology Committee of Shanghai Municipality[19ZR1418300] ; Science and Technology Committee of Shanghai Municipality[19DZ2270200] ; Independent Research and Development Project of State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University[SKLASS 2021-Z05] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000789635400006 |
| 资助机构 | National Natural Science Foundation of China ; Pioneer and Leading Goose R&D Program of Zhejiang ; Science and Technology Committee of Shanghai Municipality ; Independent Research and Development Project of State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/89042]  |
| 专题 | 力学研究所_非线性力学国家重点实验室 |
| 通讯作者 | Zhang, Yikun |
| 作者单位 | 1.Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China 2.Hangzhou Dianzi Univ, Key Lab Novel Mat Sensor Zhejiang Prov, Hangzhou 310012, Peoples R China 3.Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China 4.Shanghai Univ, Shanghai Key Lab Adv Ferromet, Shanghai 200444, Peoples R China 5.Shanghai Univ, State Key Lab Adv Special Steels, Shanghai 200444, Peoples R China 6.Hangzhou Dianzi Univ, Sch Elect & Informat Engn, Hangzhou 310012, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Zhang, Yikun,Tian, Yun,Zhang, Zhenqian,et al. Magnetic properties and giant cryogenic magnetocaloric effect in B-site ordered antiferromagnetic Gd2MgTiO6 double perovskite oxide [J]. ACTA MATERIALIA,2022,226:9. |
| APA |
Zhang, Yikun.,Tian, Yun.,Zhang, Zhenqian.,Jia, Youshun.,Zhang, Bin.,...&Jiang MQ.(2022). Magnetic properties and giant cryogenic magnetocaloric effect in B-site ordered antiferromagnetic Gd2MgTiO6 double perovskite oxide .ACTA MATERIALIA,226,9. |
| MLA |
Zhang, Yikun,et al." Magnetic properties and giant cryogenic magnetocaloric effect in B-site ordered antiferromagnetic Gd2MgTiO6 double perovskite oxide ".ACTA MATERIALIA 226(2022):9. |
入库方式： OAI收割
来源：力学研究所
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