中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters

文献类型:期刊论文

作者Wang, Dawei3; Jiang, Shenghao3; Liang, Yuanyuan3; Wang, Xiaobin3; Zhuang, Xuming3; Tian, Chunyuan3; Luan, Feng3; Chen, Lingxin1,2
刊名TALANTA
出版日期2022
卷号236页码:8
关键词Molecular imprinting Electrochemiluminescence Copper nanoclusters Enrofloxacin
ISSN号0039-9140
DOI10.1016/j.talanta.2021.122835
通讯作者Zhuang, Xuming(xmzhuang@iccas.ac.cn) ; Chen, Lingxin(lxchen@yic.ac.cn)
英文摘要Enrofloxacin (ENR) is a broad-spectrum fungicide that has been largely applied in pharmacy and animal-specific medicine. In this paper, a simple, novel and highly sensitive molecularly imprinted electrochemiluminescence (MIP-ECL) sensor based on mercaptopropionic acid-functionalized copper nanoclusters (MPA-Cu NCs) was developed to selectively detect enrofloxacin (ENR). MPA-Cu NCs prepared by a one-step method were used to modify the glassy carbon electrode. A molecularly imprinted polymer film containing the cavity was constructed after electropolymerization and elution. Under optimized conditions, the MIP-ECL sensor could detect ENR in the range of 0.1 nM(-1) mu M (R-2 = 0.9863) with a low limit of detection of 27 pM, and the recovery rates of ENR in biological and lake water samples were 88.20-105.0%. The MIP-ECL sensor provided path to improve the stability issues of Cu NCs, which might open promising avenues to develop new ECL systems for biological analysis and environmental water monitoring.
WOS关键词UP-CONVERSION NANOPARTICLES ; ELECTROCHEMICAL SENSOR ; ULTRASENSITIVE DETECTION ; SENSITIVE DETECTION ; LIQUID-CHROMATOGRAPHY ; POLYMER ; PROBE ; MILK ; CHEMILUMINESCENCE ; CIPROFLOXACIN
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000701264100005
资助机构National Natural Science Foundation of China ; Taishan Scholar Project Special Funding
源URL[http://ir.yic.ac.cn/handle/133337/30808]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_中科院烟台海岸带研究所知识产出
烟台海岸带研究所_山东省海岸带环境工程技术研究中心
通讯作者Zhuang, Xuming; Chen, Lingxin
作者单位1.Binzhou Med Univ, Sch Pharm, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
3.Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Peoples R China
推荐引用方式
GB/T 7714
Wang, Dawei,Jiang, Shenghao,Liang, Yuanyuan,et al. Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters[J]. TALANTA,2022,236:8.
APA Wang, Dawei.,Jiang, Shenghao.,Liang, Yuanyuan.,Wang, Xiaobin.,Zhuang, Xuming.,...&Chen, Lingxin.(2022).Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters.TALANTA,236,8.
MLA Wang, Dawei,et al."Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters".TALANTA 236(2022):8.

入库方式: OAI收割

来源:烟台海岸带研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。