Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters
文献类型:期刊论文
作者 | Wang, Dawei3; Jiang, Shenghao3; Liang, Yuanyuan3; Wang, Xiaobin3![]() ![]() |
刊名 | TALANTA
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出版日期 | 2022 |
卷号 | 236页码:8 |
关键词 | Molecular imprinting Electrochemiluminescence Copper nanoclusters Enrofloxacin |
ISSN号 | 0039-9140 |
DOI | 10.1016/j.talanta.2021.122835 |
通讯作者 | Zhuang, Xuming(xmzhuang@iccas.ac.cn) ; Chen, Lingxin(lxchen@yic.ac.cn) |
英文摘要 | Enrofloxacin (ENR) is a broad-spectrum fungicide that has been largely applied in pharmacy and animal-specific medicine. In this paper, a simple, novel and highly sensitive molecularly imprinted electrochemiluminescence (MIP-ECL) sensor based on mercaptopropionic acid-functionalized copper nanoclusters (MPA-Cu NCs) was developed to selectively detect enrofloxacin (ENR). MPA-Cu NCs prepared by a one-step method were used to modify the glassy carbon electrode. A molecularly imprinted polymer film containing the cavity was constructed after electropolymerization and elution. Under optimized conditions, the MIP-ECL sensor could detect ENR in the range of 0.1 nM(-1) mu M (R-2 = 0.9863) with a low limit of detection of 27 pM, and the recovery rates of ENR in biological and lake water samples were 88.20-105.0%. The MIP-ECL sensor provided path to improve the stability issues of Cu NCs, which might open promising avenues to develop new ECL systems for biological analysis and environmental water monitoring. |
WOS关键词 | UP-CONVERSION NANOPARTICLES ; ELECTROCHEMICAL SENSOR ; ULTRASENSITIVE DETECTION ; SENSITIVE DETECTION ; LIQUID-CHROMATOGRAPHY ; POLYMER ; PROBE ; MILK ; CHEMILUMINESCENCE ; CIPROFLOXACIN |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000701264100005 |
资助机构 | National Natural Science Foundation of China ; Taishan Scholar Project Special Funding |
源URL | [http://ir.yic.ac.cn/handle/133337/30808] ![]() |
专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 烟台海岸带研究所_中科院烟台海岸带研究所知识产出 烟台海岸带研究所_山东省海岸带环境工程技术研究中心 |
通讯作者 | Zhuang, Xuming; Chen, Lingxin |
作者单位 | 1.Binzhou Med Univ, Sch Pharm, Yantai 264003, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Shandong Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China 3.Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Dawei,Jiang, Shenghao,Liang, Yuanyuan,et al. Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters[J]. TALANTA,2022,236:8. |
APA | Wang, Dawei.,Jiang, Shenghao.,Liang, Yuanyuan.,Wang, Xiaobin.,Zhuang, Xuming.,...&Chen, Lingxin.(2022).Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters.TALANTA,236,8. |
MLA | Wang, Dawei,et al."Selective detection of enrofloxacin in biological and environmental samples using a molecularly imprinted electrochemiluminescence sensor based on functionalized copper nanoclusters".TALANTA 236(2022):8. |
入库方式: OAI收割
来源:烟台海岸带研究所
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