Emotions during driving have an essential impact on driving safety. This study aims to explore the relationships among emotional intelligence, emotional regulation, driving anger and related behaviour. A total of 304 drivers (aged 18–57) completed online questionnaires, including the trait emotional intelligence (TEI) scale, difficulties in emotional regulation scale (DERS), driving anger scale (DAS) and driver anger expression inventory (DAX). The results showed that the influence of TEI on maladaptive driving anger expression was negative, and individuals with higher emotional intelligence showed less maladaptive expressions of driving anger. Difficulties in emotion regulation played a mediating role between emotional intelligence and driving anger. These results suggest that drivers with high emotional intelligence and emotion regulation may face driving situations calmly and with a high level of driving safety.