Conducting Polyaniline/Au Nanorods Composite Film for High-Performance Electrochromic Device
文献类型：期刊论文
| 作者 | Feng,Tong1,2; Guo,Huili1; Zhang,Bingjie1; Qu,Xiaojie1; Bai,Yan1; Dang,Dongbin1; Zhao,Weizhen2 |
| 刊名 | Journal of The Electrochemical Society
 |
| 出版日期 | 2022-03-01 |
| 卷号 | 169期号:3 |
| ISSN号 | 0013-4651 |
| DOI | 10.1149/1945-7111/ac5659 |
| 英文摘要 | Conducting polymers are promising candidate materials in next-generation electrochromic applications due to their multicolour changes, flexible and large-scale production capability; however, poor cycling stability and relatively low optical modulation limit their widespread application. In this article, a simple electrochemical deposition method is used to create a polyaniline (PANI)/Au nanorods composite electrochromic film on ITO glass as an electrode. This PANI/Au nanorods composite film has better electrochromic properties than the straight PANI film. Moreover, the electrochromic device (ECD) was successfully fabricated by PANI/Au nanorods composite film as anode and poly(3,4-ethyloxylthiophene) as the cathode. This resultant device exhibits perfect electrochromic performance, including higher optical modulation (56%), a faster response time (0.6 s for bleaching and 0.9 s for colouring) and good cycling stability (sustained 85% after 6750 cycles). Notably, the geometric structure of the film is formed by the Au nanorods coated with PANI, which not only can provide transport channel and ion storage space but also improving the conductivity. In addition, the composite structure can provide larger surface area and benefit the electrolyte ions insertion and extraction from the composite electrode film. The rational design of stacking nanocomposites on electrodes may be a useful method for fabricating high-performance ECDs. |
| 语种 | 英语 |
| 出版者 | IOP Publishing |
| WOS记录号 | IOP:JES_169_3_036501 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/49991]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Bai,Yan; Dang,Dongbin; Zhao,Weizhen |
| 作者单位 | 1.Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, People’s Republic of China 2.Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China |
| 推荐引用方式 GB/T 7714 | Feng,Tong,Guo,Huili,Zhang,Bingjie,et al. Conducting Polyaniline/Au Nanorods Composite Film for High-Performance Electrochromic Device[J]. Journal of The Electrochemical Society,2022,169(3). |
| APA | Feng,Tong.,Guo,Huili.,Zhang,Bingjie.,Qu,Xiaojie.,Bai,Yan.,...&Zhao,Weizhen.(2022).Conducting Polyaniline/Au Nanorods Composite Film for High-Performance Electrochromic Device.Journal of The Electrochemical Society,169(3). |
| MLA | Feng,Tong,et al."Conducting Polyaniline/Au Nanorods Composite Film for High-Performance Electrochromic Device".Journal of The Electrochemical Society 169.3(2022). |
入库方式： OAI收割
来源：过程工程研究所
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