Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2
文献类型：期刊论文
| 作者 | Zhang, Zhibo1; Tong, Jiahuan1; Meng, Xianglei1; Cai, Yingjun1; Ma, Shuangshuang2; Huo, Feng2; Luo, Jianquan3; Xu, Bao-Hua2; Zhang, Suojiang2; Pinelo, Manuel1 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2021-08-30 |
| 卷号 | 9期号:34页码:11503-11511 |
| 关键词 | CO2 reduction NADH regeneration photocatalytic dehydrogenase membrane |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.1c03737 |
| 英文摘要 | NADH is a required cofactor for enzymatic hydrogenation of CO2 to methanol, but the high costs of NADH deter its large-scale application. Photocatalytic reduction of NAD(+) to NADH is a promising solution that utilizes limitless solar energy. The success of photocatalytic reduction of NAD(+) depends on the use of a photosensitizer that must enable efficient electron transfer from the photosensitizer to the catalyst. Among the evaluated photosensitizers, ionic porphyrin (ZnTPyPBr) was found to be the most efficient photosensitizer for in situ NADH regeneration. Compared to the free system (control), methanol concentration was increased sevenfold when a membrane was used as a support to integrate cascade enzymatic reaction and NADH regeneration. |
| WOS关键词 | ARTIFICIAL PHOTOSYNTHESIS SYSTEM ; MULTI-ENZYMATIC CONVERSION ; CARBON-DIOXIDE ; ELECTROCHEMICAL REDUCTION ; COFACTOR REGENERATION ; NADH REGENERATION ; SOLAR-ENERGY ; IMMOBILIZATION ; FILTRATION ; CATALYSIS |
| 资助项目 | National Science Foundation of China[U1704251] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000692546300019 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50123]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Suojiang; Pinelo, Manuel |
| 作者单位 | 1.Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 3.Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhibo,Tong, Jiahuan,Meng, Xianglei,et al. Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(34):11503-11511. |
| APA | Zhang, Zhibo.,Tong, Jiahuan.,Meng, Xianglei.,Cai, Yingjun.,Ma, Shuangshuang.,...&Pinelo, Manuel.(2021).Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(34),11503-11511. |
| MLA | Zhang, Zhibo,et al."Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.34(2021):11503-11511. |
入库方式： OAI收割
来源：过程工程研究所
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