Regulating electrochemical CO2RR selectivity at industrial current densities by structuring copper@poly(ionic liquid) interface
文献类型：期刊论文
| 作者 | Li, Xiao-Qiang1,2; Duan, Guo-Yi1; Chen, Jun-Wu1,2; Han, Li-Jun1; Zhang, Suo-Jiang1,2; Xu, Bao-Hua1,2 |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2021-11-15 |
| 卷号 | 297页码:13 |
| 关键词 | CO2 Utilization Value-added chemical synthesis Electrocatalysis Organic-inorganic hybrids |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2021.120471 |
| 英文摘要 | Ionic liquid-based electrocatalytic CO2 reduction faces the challenge of achieving high selectivity toward value-added C2+ products at high reaction rate (>= 100 mA cm(-2)). Herein, novel copper@poly(ionic liquid) (Cu@PIL) hybrids demonstrate multi-electron reduction (> 2e(-)) with current densities >= 300 mA cm(-2). Remarkably, Cu@PIL with F- anion exhibits high C2+ faradaic efficiency of 58 % with a high partial current density of 174 mA cm(-2). Further, a highest C2+ partial current density of 233 mA cm(-2) was also achieved. Experimental combined theoretical investigations reveal that the "individual" ionic pairs in the outer PIL layer enrich local CO2 concentration, thereby promoting the CO2 supply. Besides, an interfacial electric field is induced by the unbonded imidazolium moieties at Cu-PIL interface, which stabilize intermediates. Anions, differing in the electron-donating number to the imidazolium moieties, influence both the enrichment of CO2 and the stabilization of intermediates, thus regulating current density and product selectivity. |
| WOS关键词 | X-RAY PHOTOELECTRON ; CARBON-DIOXIDE ; IONIC LIQUIDS ; POLY(IONIC LIQUIDS) ; REDUCTION ; COPPER ; ELECTROREDUCTION ; XPS ; DERIVATIVES ; ELECTRODES |
| 资助项目 | Key Research Program of Frontier Sciences, CAS[ZDBS-LY-JSC022] ; Excellent Young Scientists Fund[22022815] ; National Natural Science Foundation of China[U1704251] ; National Natural Science Foundation of China[21776291] ; Zhengzhou High Level Talent Certificate[20180200052] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000696992600001 |
| 出版者 | ELSEVIER |
| 资助机构 | Key Research Program of Frontier Sciences, CAS ; Excellent Young Scientists Fund ; National Natural Science Foundation of China ; Zhengzhou High Level Talent Certificate |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50231]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Xu, Bao-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiao-Qiang,Duan, Guo-Yi,Chen, Jun-Wu,et al. Regulating electrochemical CO2RR selectivity at industrial current densities by structuring copper@poly(ionic liquid) interface[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2021,297:13. |
| APA | Li, Xiao-Qiang,Duan, Guo-Yi,Chen, Jun-Wu,Han, Li-Jun,Zhang, Suo-Jiang,&Xu, Bao-Hua.(2021).Regulating electrochemical CO2RR selectivity at industrial current densities by structuring copper@poly(ionic liquid) interface.APPLIED CATALYSIS B-ENVIRONMENTAL,297,13. |
| MLA | Li, Xiao-Qiang,et al."Regulating electrochemical CO2RR selectivity at industrial current densities by structuring copper@poly(ionic liquid) interface".APPLIED CATALYSIS B-ENVIRONMENTAL 297(2021):13. |
入库方式： OAI收割
来源：过程工程研究所
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