Synthesis, structure and property studies of a new series of rare earth (Ce, Tb) bismuth silicates
文献类型：期刊论文
| 作者 | Tao, Ce1,2; Li, Jianqiang2; Li, Rukang1,3 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2021-12-01 |
| 卷号 | 304页码:7 |
| 关键词 | Rare-earth bismuth silicate Layered structure Terbium Photoluminescene |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2021.122568 |
| 英文摘要 | A new series of rare earth bismuth silicates has been synthesized by flux method and solid state reaction. LnBiSiO5 (Ln = Ce, Tb) crystallizes in a triclinic space group P-1 with cell parameters a = 5.6763(2) angstrom, alpha = 105.591(3)degrees b = 6.7922(3) angstrom, beta = 110.551(3)degrees c = 6.9593(2) angstrom, gamma = 99.733(3) degrees, Z = 2. They exhibit a novel three-dimensional structure consisting of zig-zag chains of edge-sharing Ce/TbO8 polyhedra that are further linked by SiO4 units and Bi2O8 clusters. The optical band gap (E-g) of TbBiSiO5 was estimated to be 3.84 eV from UV-Vis-IR diffuse reflectance spectra. Photoluminescence measurements suggest that due to the cooperative interaction of Bi and Tb the excitation bands monitored at 544 nm are shifted towards longer wavelength which may favor commercial UV diode excitation. The magnetic measurements show that TbBiSiO5 exhibits paramagnetic behavior without magnetic transitions down to 1.8 K. |
| WOS关键词 | ENERGY-LEVELS ; MAGNETIC-SUSCEPTIBILITY ; CRYSTAL-STRUCTURE ; PHOTOLUMINESCENCE ; LUMINESCENCE ; DIFFRACTION ; GROWTH ; IONS ; BI3+ |
| 资助项目 | National Natural Science Foundation of China[51772304] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000698156000026 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50251]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Rukang |
| 作者单位 | 1.Chinese Acad Sci, Ctr Crystal Res & Dev, Tech Inst Phys & Chem, CAS Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn,State Key Lab Multiphase Complex S, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tao, Ce,Li, Jianqiang,Li, Rukang. Synthesis, structure and property studies of a new series of rare earth (Ce, Tb) bismuth silicates[J]. JOURNAL OF SOLID STATE CHEMISTRY,2021,304:7. |
| APA | Tao, Ce,Li, Jianqiang,&Li, Rukang.(2021).Synthesis, structure and property studies of a new series of rare earth (Ce, Tb) bismuth silicates.JOURNAL OF SOLID STATE CHEMISTRY,304,7. |
| MLA | Tao, Ce,et al."Synthesis, structure and property studies of a new series of rare earth (Ce, Tb) bismuth silicates".JOURNAL OF SOLID STATE CHEMISTRY 304(2021):7. |
入库方式： OAI收割
来源：过程工程研究所
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