Encapsulated Ni Nanoparticles within Silicalite-1 Crystals for Upgrading Phenolic Compounds to Arenes
文献类型：期刊论文
| 作者 | Zhang, Jimei1,2; Duan, Feng1; Xie, Yongbing1; Ning, Pengge1; Zhao, He1; Shi, Yanchun1,2 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2021-09-29 |
| 卷号 | 60期号:38页码:13790-13801 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.1c01856 |
| 英文摘要 | About 3-S nm Ni nanoparticles were significantly encapsulated within different crystal sizes of a silicalite-1 matrix through tailoring the hydrothermal synthesis conditions and ratios of feeding materials, which were applied in the upgrading of phenolic compounds to arenes via the hydrogenolysis route. The smaller the sizes of Ni@silicalite-1 crystals with similar Ni contents and nanoparticles, the more obvious the active centers could be characterized. The enhancement in both phenol/m-cresol conversion and benzene/toluene selectivity was obtained with the decrease in crystal sizes of Ni c1 which originated from the selective elimination of the hydroxyl group, hindrance of further hydrogenation of aromatics, and the formation of methane. Furthermore, Nipsilicalite-1 was first reported for its superior stability for more than 300 h during m-cresol conversion, which maintained a high conversion from 78.4% at 8 h to 76.2% at 334 h and aromatics yield from 73.1% at 8 h to 72.6% at 334 h. Therefore, Nigsilicalite-1 provided an alternative methodology for terminal priority to achieve selectivity control different from hydrogenation on phenyl rings via a thermodynamically favorable flat mode. Ni nanoparticles encapsulated within zeolites provided a new method to regulate the adsorption mode of reactants to modify aromatic selectivity steric effects originating from shape selectivity of the silicalite-1 matrix, which also contributed to much better stability of Ni nanoparticles. |
| WOS关键词 | M-CRESOL HYDRODEOXYGENATION ; SELECTIVE HYDRODEOXYGENATION ; PHASE HYDRODEOXYGENATION ; METAL-CLUSTERS ; CATALYSTS ; NICKEL ; CONVERSION ; KINETICS ; BENZENE ; FE |
| 资助项目 | Natural Science Foundation of China[21908225] ; Natural Science Foundation of China[51978643] ; National key research and development program[2018YFC1801501] ; Science and Technology Service Network Initiative[KFJ-STS-QYZD-081] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000703997400005 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Natural Science Foundation of China ; National key research and development program ; Science and Technology Service Network Initiative |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50313]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Shi, Yanchun |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Div Environm Engn & Technol, Beijing Engn Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jimei,Duan, Feng,Xie, Yongbing,et al. Encapsulated Ni Nanoparticles within Silicalite-1 Crystals for Upgrading Phenolic Compounds to Arenes[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021,60(38):13790-13801. |
| APA | Zhang, Jimei,Duan, Feng,Xie, Yongbing,Ning, Pengge,Zhao, He,&Shi, Yanchun.(2021).Encapsulated Ni Nanoparticles within Silicalite-1 Crystals for Upgrading Phenolic Compounds to Arenes.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,60(38),13790-13801. |
| MLA | Zhang, Jimei,et al."Encapsulated Ni Nanoparticles within Silicalite-1 Crystals for Upgrading Phenolic Compounds to Arenes".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 60.38(2021):13790-13801. |
入库方式： OAI收割
来源：过程工程研究所
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