Comprehensive kinetic model for acetylene pretreated mesoporous silica supported bimetallic Co-Ni catalyst during Fischer-Trospch synthesis
文献类型：期刊论文
| 作者 | Sun, Yong1,2; Wang, Yixiao1; He, Jun1; Yusuf, Abubakar1; Wang, Yunshan3; Yang, Gang3; Xiao, Xin3 |
| 刊名 | CHEMICAL ENGINEERING SCIENCE
 |
| 出版日期 | 2021-12-31 |
| 卷号 | 246页码:16 |
| 关键词 | Acetylene pretreatment Bimetallic Co-Ni catalyst Comprehensive kinetic Fischer-Trospch synthesis |
| ISSN号 | 0009-2509 |
| DOI | 10.1016/j.ces.2021.116828 |
| 英文摘要 | A new model by incorporating the porosity field during acetylene pretreatment (PT) into the Fischer-Trospch (FT) synthesis comprehensive kinetic is proposed for quantitatively describing the product distributions using a mesoporous silica supported Co-Ni bimetallic catalyst. Coupling the quasi-homogeneous medium model with the acetylene reaction kinetics via the Langmuir-Hinshelwood-Hou gen-Watson (LHHW) approach, the model yields good predictions for breakthrough curves, pressure drops, and permeability during PT process. The active carbidic intermediates formed by the acetylene PT engaged with the subsequent CO dissociation and 1-olefin re-adsorption associated secondary reac-tions during FT synthesis. The constructed comprehensive kinetic model can predict the olefin to paraffin ratios (OPR) versus chain length when the catalyst was pretreated. A relatively good prediction from chain length dependent model (CLD) indicates the validity of assuming that Van Waals forces play a crit-ical role during olefin re-adsorption in the secondary reactions for chain propagations once the meso-porous supported Co-Ni bimetallic catalyst was pretreated by acetylene. The proposed model successfully bridges the gaps between the PT and FT process at the investigated experimental conditions. (c) 2021 Elsevier Ltd. All rights reserved. |
| WOS关键词 | IRON-BASED CATALYST ; TROPSCH SYNTHESIS ; PRODUCT DISTRIBUTIONS ; MICROCHANNEL REACTOR ; MINERAL REACTIONS ; SLURRY REACTOR ; BED REACTOR ; MECHANISM ; DEPOSITION ; BIOMASS |
| 资助项目 | Qianjiang Talent Scheme[QJD1803014] ; Faculty Inspiration Grant of University of Nottingham[FIG2019] ; Ningbo Municipal Commonweal Key Program[2019C10033] ; Ningbo Municipal Commonweal Key Program[2019C10104] ; UNNC FoSE New Researchers Grant[NRG I01210100011] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000704281400006 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | Qianjiang Talent Scheme ; Faculty Inspiration Grant of University of Nottingham ; Ningbo Municipal Commonweal Key Program ; UNNC FoSE New Researchers Grant |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50355]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Sun, Yong; Xiao, Xin |
| 作者单位 | 1.Univ Nottingham, Key Lab Carbonaceous Wastes Proc & Proc Intensifi, Ningbo 315100, Peoples R China 2.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Perth, WA 6027, Australia 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yong,Wang, Yixiao,He, Jun,et al. Comprehensive kinetic model for acetylene pretreated mesoporous silica supported bimetallic Co-Ni catalyst during Fischer-Trospch synthesis[J]. CHEMICAL ENGINEERING SCIENCE,2021,246:16. |
| APA | Sun, Yong.,Wang, Yixiao.,He, Jun.,Yusuf, Abubakar.,Wang, Yunshan.,...&Xiao, Xin.(2021).Comprehensive kinetic model for acetylene pretreated mesoporous silica supported bimetallic Co-Ni catalyst during Fischer-Trospch synthesis.CHEMICAL ENGINEERING SCIENCE,246,16. |
| MLA | Sun, Yong,et al."Comprehensive kinetic model for acetylene pretreated mesoporous silica supported bimetallic Co-Ni catalyst during Fischer-Trospch synthesis".CHEMICAL ENGINEERING SCIENCE 246(2021):16. |
入库方式： OAI收割
来源：过程工程研究所
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