FeCo/FeCoP encapsulated in N, Mn-codoped three-dimensional fluffy porous carbon nanostructures as highly efficient bifunctional electrocatalyst with multi-components synergistic catalysis for ultra-stable rechargeable Zn-air batteries
文献类型：期刊论文
| 作者 | Chen, Yu-Ping1; Lin, Shi-Yi1; Sun, Rui-Min1; Wang, Ai-Jun1; Zhang, Lu1; Ma, Xiaohong2; Feng, Jiu-Ju1 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2022 |
| 卷号 | 605页码:451-462 |
| ISSN号 | 0021-9797 |
| 关键词 | Doped porous carbon Polyinosinic acid Multi-components Bifunctional oxygen electrocatalyst Rechargeable Zn-air batteries |
| DOI | 10.1016/j.jcis.2021.07.082 |
| 英文摘要 | Currently, it is critical but a tricky point to develop economical, high-efficiency, and durable non-precious metal electrocatalysts towards oxygen reduction and oxygen evolution reaction (ORR/OER) in rechargeable Zn-air batteries. Herein, N, Mn-codoped three-dimensional (3D) fluffy porous carbon nanostructures encapsulating FeCo/FeCoP alloyed nanoparticles (FeCo/FeCoP@NMn-CNS) are prepared by one-step pyrolysis of the metal precursors and polyinosinic acid. The optimized hybrid nanocomposite (obtained at 800 degrees C, named as FeCo/FeCoP@NMn-CNS-800) exhibits outstanding catalytic performance in the alkaline electrolyte with a half-wave potential (E-1/2) of 0.84 V for the ORR and an overpotential of 325 mV towards the OER at 10 mA cm(-2). Impressively, the FeCo/FeCoP@NMn-CNS-800-assem bled rechargeable Zn-air battery presents an open-circuit voltage of 1.522 V (vs. RHE), a peak power density of 135.0 mW cm(-2), and long-term durability by charge-discharge cycling for 200 h, surpassing commercial Pt/C + RuO2 based counterpart. This work affords valuable guidelines for exploring advanced bifunctional ORR and OER catalysts in rational construction of high-quality Zn-air batteries. (C) 2021 Elsevier Inc. All rights reserved. |
| WOS关键词 | OXYGEN-REDUCTION ; ALLOY NANOPARTICLES ; QUANTUM DOTS ; NANOTUBES ; NITROGEN ; NANOCAGES ; ELECTRODE ; REMOVAL |
| 资助项目 | National Natural Science Foun-dation of China[21805245] ; Zhejiang Public Welfare Technol-ogy Application Research Project[LGG19B050001] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| WOS记录号 | WOS:000704410200005 |
| 资助机构 | National Natural Science Foun-dation of China ; Zhejiang Public Welfare Technol-ogy Application Research Project |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50397]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Ma, Xiaohong; Feng, Jiu-Ju |
| 作者单位 | 1.Zhejiang Normal Univ, Coll Geog & Environm Sci, Coll Chem & Life Sci, Key Lab,Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Yu-Ping,Lin, Shi-Yi,Sun, Rui-Min,et al. FeCo/FeCoP encapsulated in N, Mn-codoped three-dimensional fluffy porous carbon nanostructures as highly efficient bifunctional electrocatalyst with multi-components synergistic catalysis for ultra-stable rechargeable Zn-air batteries[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2022,605:451-462. |
| APA | Chen, Yu-Ping.,Lin, Shi-Yi.,Sun, Rui-Min.,Wang, Ai-Jun.,Zhang, Lu.,...&Feng, Jiu-Ju.(2022).FeCo/FeCoP encapsulated in N, Mn-codoped three-dimensional fluffy porous carbon nanostructures as highly efficient bifunctional electrocatalyst with multi-components synergistic catalysis for ultra-stable rechargeable Zn-air batteries.JOURNAL OF COLLOID AND INTERFACE SCIENCE,605,451-462. |
| MLA | Chen, Yu-Ping,et al."FeCo/FeCoP encapsulated in N, Mn-codoped three-dimensional fluffy porous carbon nanostructures as highly efficient bifunctional electrocatalyst with multi-components synergistic catalysis for ultra-stable rechargeable Zn-air batteries".JOURNAL OF COLLOID AND INTERFACE SCIENCE 605(2022):451-462. |
入库方式： OAI收割
来源：过程工程研究所
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