Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles
文献类型：期刊论文
| 作者 | Hu, Yezi1,2; Shen, Zewen1; Li, Bingfeng1; Li, Shaojun1; Yue, Junrong3; Zhao, Guixia1,2; Muhler, Martin4; Wang, Xiangke1 |
| 刊名 | ACS APPLIED NANO MATERIALS
 |
| 出版日期 | 2021-09-24 |
| 卷号 | 4期号:9页码:9254-9264 |
| 关键词 | solvent effects adsorption selective oxidation photocatalysis SrTiO3 nanoparticles |
| ISSN号 | 2574-0970 |
| DOI | 10.1021/acsanm.1c01750 |
| 英文摘要 | Photocatalytic selective oxidation of alcohols under mild conditions is an emerging technique to encounter the global challenges of energy source shortages and the green synthesis perspective. Herein, we investigate the solvent effects on heterogeneous photocatalytic anaerobic oxidation of benzyl alcohol with Pt-loaded defective SrTiO3 nanoparticles. It is found that the optimal solvent is water mixed with a small amount of dimethylformamide (DMF) or acetonitrile, while the solvent effects on the oxidation of benzyl alcohol are related to the adsorption of benzyl alcohol and benzaldehyde on the photocatalysts in different solvents, in which the adsorption of benzyl alcohol plays a major role, while such positive effect can be significantly offset in case the adsorption of benzaldehyde is leading the effort. This work offers the avenue to improve the photocatalytic oxidation of alcohols by optimizing the reaction solvents in addition to the well-known structure engineering of the photocatalysts. |
| WOS关键词 | SELECTIVE OXIDATION ; DOPED SRTIO3 ; AROMATIC ALCOHOLS ; CARBON NITRIDE ; DRIVEN ; DEHYDROGENATION ; HYDROGEN ; WATER ; ADSORPTION ; ALDEHYDES |
| 资助项目 | National Natural Science Foundation of China[21976054] ; Fundamental Research Funds for the Central Universities[2020MS036] ; National Key Research and Development Program of China[2017YFA0207002] ; Deutsche Forschungsgemeinschaft (DFG)[SFB/TRR 247] ; Beijing Outstanding Young Scientist Program |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000702079900061 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; National Key Research and Development Program of China ; Deutsche Forschungsgemeinschaft (DFG) ; Beijing Outstanding Young Scientist Program |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50408]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhao, Guixia; Wang, Xiangke |
| 作者单位 | 1.North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China 2.Ruhr Univ Bochum, Fac Chem & Biochem, Lab Ind Chem, D-44780 Bochum, Germany 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multi Phase Complex Syst, Beijing 100190, Peoples R China 4.Max Planck Inst Chem Energy Convers, D-45470 Mulheim, Germany |
| 推荐引用方式 GB/T 7714 | Hu, Yezi,Shen, Zewen,Li, Bingfeng,et al. Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles[J]. ACS APPLIED NANO MATERIALS,2021,4(9):9254-9264. |
| APA | Hu, Yezi.,Shen, Zewen.,Li, Bingfeng.,Li, Shaojun.,Yue, Junrong.,...&Wang, Xiangke.(2021).Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles.ACS APPLIED NANO MATERIALS,4(9),9254-9264. |
| MLA | Hu, Yezi,et al."Solvent Effects on Photocatalytic Anaerobic Oxidation of Benzyl Alcohol over Pt-Loaded Defective SrTiO3 Nanoparticles".ACS APPLIED NANO MATERIALS 4.9(2021):9254-9264. |
入库方式： OAI收割
来源：过程工程研究所
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