Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation
文献类型：期刊论文
| 作者 | Wang, Gang1,2; Li, Zengxi1,2; Li, Chunshan3,4 |
| 刊名 | CHEMICAL ENGINEERING SCIENCE
 |
| 出版日期 | 2022-01-16 |
| 卷号 | 247页码:13 |
| 关键词 | Acrylic acid Methyl acrylate Aldol reaction Mechanism Kinetics Separation |
| ISSN号 | 0009-2509 |
| DOI | 10.1016/j.ces.2021.117052 |
| 英文摘要 | With the gradual depletion of petroleum resources, the one-step synthesis of acrylic acid/ methyl acrylate from acetic acid/methyl acetate and formaldehyde via aldol reaction, instead of propylene selective oxidation, has stimulated researchers' interest. Current research in this field focus on catalyst modifica-tion, structure-activity relationships, catalytic mechanism and kinetics, and separation process design. The faced challenging problems are efficient catalyst development, mechanism-based kinetics calculation for reactor design and separation process optimization, which hinder the industrial progress, although great efforts have been made in the last decades. Therefore, it is necessary and meaningful to review the achievements as the basis for the further exploration and application in this area. This review aims to systematically summarize and analyze the catalytic performance and structure-activity relationships of developed catalysts, catalytic mechanism and kinetics, and separation process design, as well as sug-gest the prospective research. (c) 2021 Elsevier Ltd. All rights reserved. |
| WOS关键词 | TITANIUM BINARY PHOSPHATE ; ACETIC-ACID ; CONDENSATION REACTION ; SELECTIVE OXIDATION ; IONIC LIQUID ; ACETATE ; FORMALDEHYDE ; OXIDE ; METHANOL ; PERFORMANCE |
| 资助项目 | National Science Found for Distinguished Young Scholars[22025803] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH022] ; National Natural Science Foundation of China[21878293] ; National Natural Science Foundation of China[21676270] ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM-2019-A14] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000705826400013 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Science Found for Distinguished Young Scholars ; Key Research Program of Frontier Sciences, CAS ; National Natural Science Foundation of China ; Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50455]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Zengxi |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 101408, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Gang,Li, Zengxi,Li, Chunshan. Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation[J]. CHEMICAL ENGINEERING SCIENCE,2022,247:13. |
| APA | Wang, Gang,Li, Zengxi,&Li, Chunshan.(2022).Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation.CHEMICAL ENGINEERING SCIENCE,247,13. |
| MLA | Wang, Gang,et al."Recent progress in one-step synthesis of acrylic acid and methyl acrylate via aldol reaction: Catalyst, mechanism, kinetics and separation".CHEMICAL ENGINEERING SCIENCE 247(2022):13. |
入库方式： OAI收割
来源：过程工程研究所
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