Mn-Doped Highly Dispersed RuO2 Catalyst with Abundant Oxygen Vacancies for Efficient Decarboxylation of L-Lysine to Cadaverine
文献类型：期刊论文
| 作者 | Ma, Zhanling1,2; Xin, Zongwu1; Qin, Shaojie1; Huang, Yuhong1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2021-10-11 |
| 卷号 | 9期号:40页码:13480-13490 |
| 关键词 | Decarboxylation L-Lysine Cadaverine Ruthenium oxides Oxygen vacancies |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.1c04272 |
| 英文摘要 | Chemical decarboxylation of L-lysine is a promising route for producing cadaverine, which is the key monomer of new polyamide, polyurethane, and nylon materials. Currently, the wide application of Ru-based catalysts is restricted by its low efficiency which was mainly caused by the severe agglomeration of ruthenium nanoparticle. In this study, manganese (Mn) doped ruthenium oxide catalyst was synthesized through the wetness impregnation method with Beta zeolite as the candidate support for efficient decarboxylation of L-lysine to cadaverine. Structure characterization showed that RuO2 was the main phase of ruthenium oxide nanoparticles. The prepared Ru-Mn/Beta catalysts exhibited a high dispersion of ruthenium oxide nanaoparticle on Beta, which maximized the utilization of active sites. Meanwhile, abundant oxygen vacancies were generated after Mn doping to balance the charge of the disturbed long-term periodic structure in the RuO2 crystalline, which greatly facilitated the adsorption and activation of L-lysine by the capture of carboxylic groups. A full conversion was obtained with Ru-Mn/Beta, and a selectivity of cadaverine up to 54% was reached in a short time of 1.5 h. The cadaverine production rate in Ru-Mn/Beta was 60.8 mg/L/min, which was almost triple that in Ru/Beta (17.7 mg/L/min). The synergetic catalysis of metal active sites and oxygen vacancies provides a new opportunity to design efficient catalyst of decarboxylation of amino acids. |
| WOS关键词 | MANGANESE OXIDE CATALYSTS ; EVOLUTION REACTION ; CO3O4 NANOSHEETS ; OXIDATION ; HYDROGENATION ; RUTHENIUM ; RICH ; NANOPARTICLES ; REDUCTION ; CHEMISTRY |
| 资助项目 | China Postdoctoral Science Foundation[2021M690920] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000708391800010 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | China Postdoctoral Science Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50723]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Ma, Zhanling; Huang, Yuhong |
| 作者单位 | 1.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Henan, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Zhanling,Xin, Zongwu,Qin, Shaojie,et al. Mn-Doped Highly Dispersed RuO2 Catalyst with Abundant Oxygen Vacancies for Efficient Decarboxylation of L-Lysine to Cadaverine[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(40):13480-13490. |
| APA | Ma, Zhanling,Xin, Zongwu,Qin, Shaojie,&Huang, Yuhong.(2021).Mn-Doped Highly Dispersed RuO2 Catalyst with Abundant Oxygen Vacancies for Efficient Decarboxylation of L-Lysine to Cadaverine.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(40),13480-13490. |
| MLA | Ma, Zhanling,et al."Mn-Doped Highly Dispersed RuO2 Catalyst with Abundant Oxygen Vacancies for Efficient Decarboxylation of L-Lysine to Cadaverine".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.40(2021):13480-13490. |
入库方式： OAI收割
来源：过程工程研究所
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