Atomically Dispersed Ruthenium on Nickel Hydroxide Ultrathin Nanoribbons for Highly Efficient Hydrogen Evolution Reaction in Alkaline Media
文献类型：期刊论文
| 作者 | Chen, Xiaoyu2,3; Wan, Jiawei4; Wang, Jin3; Zhang, Qinghua5; Gu, Lin5; Zheng, Lirong1; Wang, Na2; Yu, Ranbo2,6 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2021-11-01 |
| 卷号 | 33期号:44页码:9 |
| 关键词 | hydrogen evolution reaction nickel hydroxide ruthenium atomic site ultrathin nanoribbons |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.202104764 |
| 英文摘要 | Achieving highly efficient hydrogen evolution reaction (HER) in alkaline media is a great challenge. Single-atom catalysts with high-loading amount have attracted great interest due to their remarkable catalytic properties. Herein, by using nickel foam as the substrate, the authors design and precisely synthesize atomic ruthenium (Ru)-loaded nickel hydroxide ultrathin nanoribbons (R-NiRu) with a high atomic Ru loading amount reaching approximate to 7.7 wt% via a one-step hydrothermal method. The presence of concentrated Cl- in the synthetic system is beneficial for constructing ultrathin nanoribbons, which, with abundant edge -OH groups, make it easy to trap atomic Ru. Taking advantage of the synergy between atomic Ru and the nanoribbon morphology of nickel hydroxide, R-NiRu exhibit a low overpotential of 16 mV for HER at 10 mA cm(-2) and a Tafel slope of 40 mV dec(-1) in aqueous 1.0 m KOH solution, which are superior to those of commercial Pt/C (overpotential of 17 mV at 10 mA cm(-2), Tafel slope of 43 mV dec(-1)). Density functional theory (DFT) calculation results demonstrate that atomically dispersed Ru can significantly reduce the HER energy barrier. Moreover, R-NiRu maintains exceptional stability after 5000 cyclic voltammetry cycles. This efficient and facile synthetic strategy provides a new avenue for designing efficient catalysts. |
| WOS关键词 | LAYERED DOUBLE HYDROXIDE ; TOTAL-ENERGY CALCULATIONS ; ORGANIC FRAMEWORKS ; SINGLE ; CATALYST ; MECHANISM ; ELECTROCATALYST ; ADSORPTION ; NANOWIRES ; ROUTE |
| 资助项目 | National Natural Science Foundation of China[51802306] ; National Natural Science Foundation of China[51932001] ; National Natural Science Foundation of China[52022097] ; National Natural Science Foundation of China[51872024] ; Foundation of Youth Innovation Promotion Association of CAS[2020048] ; National Key Research and Development Program of China[2018YFA0703503] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000713289800009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Foundation of Youth Innovation Promotion Association of CAS ; National Key Research and Development Program of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/50816]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wan, Jiawei; Wang, Jin; Yu, Ranbo |
| 作者单位 | 1.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China 2.Univ Sci & Technol Beijing, Sch Met & Ecol Engn, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China 3.Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China 6.Zhengzhou Univ, Minist Educ, Key Lab Adv Mat Proc & Mold, Zhengzhou 450002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Xiaoyu,Wan, Jiawei,Wang, Jin,et al. Atomically Dispersed Ruthenium on Nickel Hydroxide Ultrathin Nanoribbons for Highly Efficient Hydrogen Evolution Reaction in Alkaline Media[J]. ADVANCED MATERIALS,2021,33(44):9. |
| APA | Chen, Xiaoyu.,Wan, Jiawei.,Wang, Jin.,Zhang, Qinghua.,Gu, Lin.,...&Yu, Ranbo.(2021).Atomically Dispersed Ruthenium on Nickel Hydroxide Ultrathin Nanoribbons for Highly Efficient Hydrogen Evolution Reaction in Alkaline Media.ADVANCED MATERIALS,33(44),9. |
| MLA | Chen, Xiaoyu,et al."Atomically Dispersed Ruthenium on Nickel Hydroxide Ultrathin Nanoribbons for Highly Efficient Hydrogen Evolution Reaction in Alkaline Media".ADVANCED MATERIALS 33.44(2021):9. |
入库方式： OAI收割
来源：过程工程研究所
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