中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 过程工程研究所
  3. 中国科学院过程工程研究所
Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol

文献类型：期刊论文

作者Li, Huilin1; Guo, Qiang2; Li, Yongli2; Fu, Mingbo1; Tian, Dengchao1; Qi, Tao2
刊名JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
出版日期2021-10-01
卷号9期号:5页码:13
关键词CeO2 Expanded graphite Adsorption Photocatalysis Phenol
DOI10.1016/j.jece.2021.106252
英文摘要A facile solution to obtain efficient, stable and cheap photocatalysts was conducted in this work. CeO2@ expanded graphite (CeO2/EG) composites were in-situ synthesized with a new strategy, in which CeCl3 molecules inserted the graphite intercalation compound (GIC) and converted into CeO2 as GIC changed into EG via instant calcination. The introduction of EG has accelerated the adsorption of contaminant molecules, promoted the charge transfer and improved the photocatalytic efficiency. The best sample, containing 80.75 wt% CeO2 particles of nanometer scale, has achieved the highest pollutant removal efficiency of 97.3% for phenol, displaying the highest reaction rate constant of 0.0262 min(-1), which was 35.4 times higher than CeO2. Besides, it possesses good stability and keeps floating in water pollution treatment, showing great advantages to work in natural water body. Phenol and its degradation intermediates were identified using HPLC/MS, and appropriate reaction pathways were proposed.
WOS关键词SURFACE ; OXIDE ; TIO2 ; HETEROSTRUCTURES ; NANOSTRUCTURES ; PERFORMANCE ; FABRICATION ; GRAPHENE ; CERIA
资助项目National Key Research and Development Projects of China[2020YFC1909601] ; National Key Research and Development Projects of China[2020YFC1909603] ; Key Deployment Projects of Chinese Academy of Sciences[ZDRWZS201811] ; Key Research and Devel-opment and Promotion Projects of Henan Province[212102310066]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000714646000002
出版者ELSEVIER SCI LTD
资助机构National Key Research and Development Projects of China ; Key Deployment Projects of Chinese Academy of Sciences ; Key Research and Devel-opment and Promotion Projects of Henan Province
源URL[http://ir.ipe.ac.cn/handle/122111/50883]  
专题中国科学院过程工程研究所
通讯作者Guo, Qiang; Qi, Tao
作者单位1.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450003, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714		 Li, Huilin,Guo, Qiang,Li, Yongli,et al. Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2021,9(5):13.
APA Li, Huilin,Guo, Qiang,Li, Yongli,Fu, Mingbo,Tian, Dengchao,&Qi, Tao.(2021).Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,9(5),13.
MLA Li, Huilin,et al."Facile in-situ synthesis of floating CeO2@ expanded graphite composites with efficient adsorption and visible light photocatalytic degradation of phenol".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 9.5(2021):13.

入库方式： OAI收割

来源：过程工程研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。