Construction of Ti4O7/TiN/carbon microdisk sulfur host with strong polar N-Ti-O bond for ultralong life lithium-sulfur battery
文献类型：期刊论文
| 作者 | Ma, Linlin4; Yu, Li-Juan6; Liu, Jingchong2,3,5; Su, Ya-Qiong7; Li, Shuai5; Zang, Xiaohuan4; Meng, Tao4; Zhang, Shuaihua4; Song, Jianjun8; Wang, Jiangyan1 |
| 刊名 | ENERGY STORAGE MATERIALS
 |
| 出版日期 | 2022 |
| 卷号 | 44页码:180-188 |
| ISSN号 | 2405-8297 |
| 关键词 | Heterostructure Interface control Ti4O7/TiN/C microdisk Sulfur host lithium-sulfur battery |
| DOI | 10.1016/j.ensm.2021.09.024 |
| 英文摘要 | As the desired sulfur host of lithium-sulfur battery, the strong polarity and fast electron migration capability are indispensable for achieving effective adsorption and conversion of lithium polysulfides (LiPSs), that is, restrict-ing the shuttle effect. Herein a porous microdisk Ti4O7/TiN/C heterojunction with strong polar N-Ti-O covalent bonds is precisely constructed. Compared with O-Ti-O or N-Ti-N bond in single Ti4O7 or TiN, the N-Ti-O bond with stronger polarity could adsorb and bond with S and Li atoms in LiPSs, which is beneficial for LiPSs adsorption. Beside, the Ti4O7/TiN heterostructure favors the electron transfer, which could promote the conversion of LiPSs. The design strategy is to construct abundant polar N-Ti-O bonds at Ti4O7/TiN heterogeneous interface that would realize the associative process of LiPSs adsorption, trapping, and conversion, thereby restraining the shuttle effect efficiently. In the current study, as the host of the sulfur cathode, the porous microdisk TiN/Ti4O7 /C heterojunc-tion exhibits a high specific capacity of 1204.5 mAh g(-1) at 0.2 C, and a high specific capacity of 616.5 mAh g(-1) at an ultrahigh current density of 4 C. In addition, 86.4% and 116.9% capacity are retained over 1000 cycles at 1 C and 2 C, respectively. This strategy provides an insight into developing lithium-sulfur battery with extraordinary performance, and opens promising routes to design the next-generation electrochemical energy storage devices. |
| WOS关键词 | TOTAL-ENERGY CALCULATIONS ; CARBON NANOFIBERS ; LONG-LIFE ; POLYSULFIDES ; CONVERSION ; CATHODE ; HETEROSTRUCTURES ; INTERLAYER ; EFFICIENCY ; NANOSHEETS |
| 资助项目 | Natural Science Foundation of Hebei Province[B2019204009] ; Talents Introduction Plan of Hebei Agri-cultural University[YJ201810] ; National Natural Science Foundation of China (NSFC)[22105059] ; National Natural Science Foundation of China (NSFC)[22005012] ; China Postdoctoral Science Foundation[2019M650431] ; National Post-doctoral Program for Innovative Talents[BX20190027] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:000718172000001 |
| 资助机构 | Natural Science Foundation of Hebei Province ; Talents Introduction Plan of Hebei Agri-cultural University ; National Natural Science Foundation of China (NSFC) ; China Postdoctoral Science Foundation ; National Post-doctoral Program for Innovative Talents |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51156]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Jingchong; Zhao, Xiaoxian; Zhao, Yong |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 Beierjie, Beijing 100190, Peoples R China 2.Tech Inst Phys & Chem Beijing, CAS Key Lab Bioinspired Mat & Interfacial Sci, Beijing 100190, Peoples R China 3.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing, Peoples R China 4.Hebei Agr Univ, Coll Sci, Dept Chem, Baoding 071001, Peoples R China 5.Beihang Univ, Beijing Adv Innovat Ctr Biomed Engn, Key Lab Bioinspired Smart Interfacial Sci & Techn, Sch Chem,Minist Educ, Beijing 100191, Peoples R China 6.Australian Natl Univ, Res Sch Chem, Canberra, ACT 2601, Australia 7.Xi An Jiao Tong Univ, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian Key Lab Sustainable Energy Mat Chem, Sch Chem,State Key Lab Elect Insulat & Power Equi, Xian 710049, Peoples R China 8.Qingdao Univ, Coll Phys, Qingdao 266071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Linlin,Yu, Li-Juan,Liu, Jingchong,et al. Construction of Ti4O7/TiN/carbon microdisk sulfur host with strong polar N-Ti-O bond for ultralong life lithium-sulfur battery[J]. ENERGY STORAGE MATERIALS,2022,44:180-188. |
| APA | Ma, Linlin.,Yu, Li-Juan.,Liu, Jingchong.,Su, Ya-Qiong.,Li, Shuai.,...&Zhao, Yong.(2022).Construction of Ti4O7/TiN/carbon microdisk sulfur host with strong polar N-Ti-O bond for ultralong life lithium-sulfur battery.ENERGY STORAGE MATERIALS,44,180-188. |
| MLA | Ma, Linlin,et al."Construction of Ti4O7/TiN/carbon microdisk sulfur host with strong polar N-Ti-O bond for ultralong life lithium-sulfur battery".ENERGY STORAGE MATERIALS 44(2022):180-188. |
入库方式： OAI收割
来源：过程工程研究所
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