Bipolar Membrane Electrodialysis for Ammonia Recovery from Synthetic Urine: Experiments, Modeling, and Performance Analysis
文献类型：期刊论文
| 作者 | Li, Yujiao4,5,6; Wang, Ruoyu4,6; Shi, Shaoyuan4,5,6; Cao, Hongbin4,5,6; Yip, Ngai Yin1,2; Lin, Shihong3,4 |
| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2021-11-02 |
| 卷号 | 55期号:21页码:14886-14896 |
| 关键词 | nutrient recovery bipolar membrane electrodialysis membrane contactor source-separated urine performance analysis |
| ISSN号 | 0013-936X |
| DOI | 10.1021/acs.est.1c05316 |
| 英文摘要 | Recovering nitrogen from source-separated urine is an important part of the sustainable nitrogen management. A novel bipolar membrane electrodialysis with membrane contactor (BMED-MC) process is demonstrated here for efficient recovery of ammonia from synthetic source-separated urine (similar to 3772 mg N L-1). In a BMED-MC process, electrically driven water dissociation in a bipolar membrane simultaneously increases the pH of the urine stream and produces an acid stream for ammonia stripping. With the increased pH of urine, ammonia transports across the gas-permeable membrane in the membrane contactor and is recovered by the acid stream as ammonium sulfate that can be directly used as fertilizer. Our results obtained using batch experiments demonstrate that the BMED-MC process can achieve 90% recovery. The average ammonia flux and the specific energy consumption can be regulated by varying the current density. At a current density of 20 mA cm(-2), the energy required to achieve a 67.5% ammonia recovery in a 7 h batch mode is 92.8 MJ kg(-1) N for a bench-scale system with one membrane stack and can approach 25.8 MJ kg(-1) N for large-scale systems with multiple membrane stacks, with an average ammonia flux of 2.2 mol m(-2) h(-1). Modeling results show that a continuous BMED-MC process can achieve a 90% ammonia recovery with a lower energy consumption (i.e., 12.5 MJ kg(-1) N). BMED-MC shows significant potential for ammonia recovery from source-separated urine as it is relatively energy-efficient and requires no external acid solution. |
| WOS关键词 | SOURCE-SEPARATED URINE ; NITROGEN ; REMOVAL ; AGRICULTURE ; EXTRACTION ; CELL |
| 资助项目 | National Science Foundation[1903685] ; National Science Foundation[1903705] ; Chinese Scholarship Council[201904910827] |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000714110200059 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Science Foundation ; Chinese Scholarship Council |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51170]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Lin, Shihong |
| 作者单位 | 1.Columbia Univ, Dept Earth & Environm Engn, New York, NY 10027 USA 2.Columbia Univ, Columbia Water Ctr, New York, NY 10027 USA 3.Vanderbilt Univ, Dept Chem & Bimol Engn, Nashville, TN 37235 USA 4.Vanderbilt Univ, Dept Civil & Environm Engn, Nashville, TN 37235 USA 5.Chinese Acad Sci, Inst Proc Engn, Beijing Engn Res Ctr Proc Pollut Control, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 6.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yujiao,Wang, Ruoyu,Shi, Shaoyuan,et al. Bipolar Membrane Electrodialysis for Ammonia Recovery from Synthetic Urine: Experiments, Modeling, and Performance Analysis[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2021,55(21):14886-14896. |
| APA | Li, Yujiao,Wang, Ruoyu,Shi, Shaoyuan,Cao, Hongbin,Yip, Ngai Yin,&Lin, Shihong.(2021).Bipolar Membrane Electrodialysis for Ammonia Recovery from Synthetic Urine: Experiments, Modeling, and Performance Analysis.ENVIRONMENTAL SCIENCE & TECHNOLOGY,55(21),14886-14896. |
| MLA | Li, Yujiao,et al."Bipolar Membrane Electrodialysis for Ammonia Recovery from Synthetic Urine: Experiments, Modeling, and Performance Analysis".ENVIRONMENTAL SCIENCE & TECHNOLOGY 55.21(2021):14886-14896. |
入库方式： OAI收割
来源：过程工程研究所
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