Regulated Electrodeposition of Na Metal in Monolithic ZIF-Pillared Graphene Anodes
文献类型：期刊论文
| 作者 | He, Qiya1,3; Jin, Xin2,4; Li, Zhonghua2,4; Cai, Ziqiang2,4; Tian, Jiaming2,4; Hui, Junfeng3; Zhang, Huigang1,2,3,4 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2021-12-20 |
| 页码 | 9 |
| 关键词 | sodium-metal anodes Na-ion batteries deposition regulation dendrites interlayer plating |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.1c21841 |
| 英文摘要 | Sodium (Na) metal batteries receive increasing attention because of their high energy densities and low costs that are enabled by the abundant Na resources. However, dendritic growth and low efficiency of Na-metal anodes limit the practical applications of Na-metal batteries. Here, we propose a three-dimensionally pillared structure in which carbonized nanoparticles of zeolite imidazolate framework-8 (ZIF-8) are sandwiched between reduced graphene oxide (rGO) sheets (ZIF-8-C@rGO). Such a pillared structure enables two advantages over rGO. First, the sodiation products of ZIF-8 (NaZn13, Na2O, and N-doped carbon) have a strong chemical affinity to Na metal, thereby inducing favorable nucleation of Na metal to guide Na deposition. Second, the pillared structure could facilitate the diffusion of Na ions through rGO sheets and help homogenize the current distribution, leading to a uniform deposition of Na metal. As a result, ZIF-8-C@rGO exhibits a dendrite-free morphology during Na plating/stripping and excellent cycling stability with high Coulombic efficiency of over 99.8% for at least 2000 h. A symmetric cell could maintain more than 4000 h with a stable average overpotential of only 30 mV at a capacity of 1 mA h cm(-2). This work demonstrates that the design of a ZIF-pillared structure could combine thermodynamic and kinetic regulating factors to offer an alternative solution to the development of durable Na electrodes for high-performance Na-metal batteries. |
| WOS关键词 | LI ; NANOCRYSTALS |
| 资助项目 | National Key Research and Development Program of China[2020YFA0406104] ; National Natural Science Foundation of China[22075131] ; National Natural Science Foundation of China[22078265] ; State Key Laboratory of Multiphase Complex Systems[MPCS2021-A] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000734507500001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; State Key Laboratory of Multiphase Complex Systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51556]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Hui, Junfeng; Zhang, Huigang |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Nanjing Univ, Coll Engn & Appl Sci, Nanjing 210093, Peoples R China 3.Northwest Univ, Shaanxi R&D Ctr Biomat & Fermentat Engn, Sch Chem Engn, Shaanxi Key Lab Degradable Biomed Mat, Xian 710069, Shaanxi, Peoples R China 4.Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Qiya,Jin, Xin,Li, Zhonghua,et al. Regulated Electrodeposition of Na Metal in Monolithic ZIF-Pillared Graphene Anodes[J]. ACS APPLIED MATERIALS & INTERFACES,2021:9. |
| APA | He, Qiya.,Jin, Xin.,Li, Zhonghua.,Cai, Ziqiang.,Tian, Jiaming.,...&Zhang, Huigang.(2021).Regulated Electrodeposition of Na Metal in Monolithic ZIF-Pillared Graphene Anodes.ACS APPLIED MATERIALS & INTERFACES,9. |
| MLA | He, Qiya,et al."Regulated Electrodeposition of Na Metal in Monolithic ZIF-Pillared Graphene Anodes".ACS APPLIED MATERIALS & INTERFACES (2021):9. |
入库方式： OAI收割
来源：过程工程研究所
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