A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation
文献类型：期刊论文
| 作者 | Liu, Shuaifeng1,2; Zhang, Xiaojuan1,3; Asselin, Edouard3; Li, Zhibao1 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2021-12-28 |
| 页码 | 10 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.1c04211 |
| 英文摘要 | The reaction kinetics of peracetic acid from acetic acid and hydrogen peroxide in a helical capillary microreactor was investigated and modeled via regression of the measured conversion rate of hydrogen peroxide. It was found that the activity of the proton in the sulfuric acid solution played a significant role in the synthesis as a catalyst. The activities of the proton were calculated with the ELECNRTL equation and used to obtain a kinetic model with apparent activation energies of peracetic acid synthesis and hydrolysis of 53.63 and 54.45 kJ/mol, respectively. A new continuous process for industrial manufacture of peracetic acid solution (30 wt %) was proposed, where the reacted solution from the microreactor is distilled to separate unreacted reactants and sulfuric acid, which are recycled as a feed. The feasibility of the new process was validated by Aspen Plus simulation and economic assessment. |
| WOS关键词 | WASTE-WATER ; FLOW |
| 资助项目 | National Science Foundation of China[21506218] ; National Science Foundation of China[21476235] ; National Science Foundation of China[U1407112] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000737866900001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51593]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Asselin, Edouard; Li, Zhibao |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China 3.Univ British Columbia, Dept Mat Engn, Vancouver, BC V6T 1Z4, Canada |
| 推荐引用方式 GB/T 7714 | Liu, Shuaifeng,Zhang, Xiaojuan,Asselin, Edouard,et al. A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2021:10. |
| APA | Liu, Shuaifeng,Zhang, Xiaojuan,Asselin, Edouard,&Li, Zhibao.(2021).A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,10. |
| MLA | Liu, Shuaifeng,et al."A New Process for Peracetic Acid Production from Acetic Acid and Hydrogen Peroxide Based on Kinetic Modeling and Distillation Simulation".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021):10. |
入库方式： OAI收割
来源：过程工程研究所
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