Discovering and Demonstrating a Novel High-Performing 2D-Patterned Electrode for Proton-Exchange Membrane Water Electrolysis Devices
文献类型：期刊论文
| 作者 | Kang, Zhenye1,2; Chen, Yingying1,3; Wang, Hao1,4; Alia, Shaun M.1; Pivovar, Bryan S.1; Bender, Guido1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2022-01-02 |
| 页码 | 8 |
| ISSN号 | 1944-8244 |
| 关键词 | water electrolysis patterned electrode edge effect mass activity oxygen evolution reaction |
| DOI | 10.1021/acsami.1c20525 |
| 英文摘要 | Proton-exchange membrane water electrolysis (PEMWE) produces hydrogen with high efficiency and purity but uses high-loading platinum-group metal (PGM) catalysts. Such concerns call for the development of novel electrode architectures to improve catalyst utilization and mass activity, thus promoting PEMWE cost competitiveness for large-scale implementation. In this study, we demonstrated, for the first time, a novel two-dimensional (2D)-patterned electrode with edge effects to address these challenges. The edge effect was induced by membrane properties, potential distribution, and counter electrode coverage and could be optimized by tuning the catalyst layer dimensions. To achieve identical PEMWE performance, the optimal pattern saved the 21% anode PGM catalyst compared with the conventional catalyst fully covered electrode. The PGM catalyst could be further reduced by 61% to boost mass activity with no significant performance loss. The results also indicated that the electrode uniformity in PEMWE cells might not be as critical as that in PEM fuel cells. The novel 2D-patterned electrode could effectively reduce PGM catalyst loading, accelerating affordable and large-scale production of hydrogen and other value-added chemicals via electrolysis. |
| WOS关键词 | LIQUID/GAS DIFFUSION LAYERS ; HYDROGEN EVOLUTION REACTION ; IRIDIUM OXIDE LOADINGS ; EFFICIENT ; CATALYSTS ; CELLS ; ELECTROCATALYST |
| 资助项目 | U.S. Department of Energy (DOE)[DE-AC36-08GO28308] ; U.S. Department of Energy Office of Energy Efficiency and Renewable Energy (EERE) Hydrogen and Fuel Cell Technologies Office (HFTO) ; NREL under the Technology Transfer Mission Share Funding Pool[NREL ROI19-160] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000740269500001 |
| 资助机构 | U.S. Department of Energy (DOE) ; U.S. Department of Energy Office of Energy Efficiency and Renewable Energy (EERE) Hydrogen and Fuel Cell Technologies Office (HFTO) ; NREL under the Technology Transfer Mission Share Funding Pool |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51612]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Kang, Zhenye; Bender, Guido |
| 作者单位 | 1.Natl Renewable Energy Lab NREL, Chem & Nanosci Ctr, Golden, CO 80401 USA 2.Hainan Univ, Sch Chem Engn & Technol, Hainan Prov Key Lab Fine Chem, State Key Lab Marine Resource Utilizat South Chin, Haikou, Hainan, Peoples R China 3.WL Gore & Associates, Elkton, MD 21921 USA 4.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Zhenye,Chen, Yingying,Wang, Hao,et al. Discovering and Demonstrating a Novel High-Performing 2D-Patterned Electrode for Proton-Exchange Membrane Water Electrolysis Devices[J]. ACS APPLIED MATERIALS & INTERFACES,2022:8. |
| APA | Kang, Zhenye,Chen, Yingying,Wang, Hao,Alia, Shaun M.,Pivovar, Bryan S.,&Bender, Guido.(2022).Discovering and Demonstrating a Novel High-Performing 2D-Patterned Electrode for Proton-Exchange Membrane Water Electrolysis Devices.ACS APPLIED MATERIALS & INTERFACES,8. |
| MLA | Kang, Zhenye,et al."Discovering and Demonstrating a Novel High-Performing 2D-Patterned Electrode for Proton-Exchange Membrane Water Electrolysis Devices".ACS APPLIED MATERIALS & INTERFACES (2022):8. |
入库方式： OAI收割
来源：过程工程研究所
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