Recovery of Ti from titanium white waste acid with N1923 extraction and leaching of low-grade pyrolusite using raffinate
文献类型：期刊论文
| 作者 | Ju, Jinrong1,2,3; Feng, Yali2; Li, Haoran1,3 |
| 刊名 | ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2022-01-11 |
| 页码 | 12 |
| 关键词 | manganese leaching N1923 pyrolusite titanium extraction titanium white waste acid |
| ISSN号 | 1932-2135 |
| DOI | 10.1002/apj.2743 |
| 英文摘要 | Titanium dioxide industry produces a large amount of titanium white waste acid every year. In this work, to make full use of and recover valuable components in titanium white waste acid, a processing for recovery of Ti from titanium white waste acid with N1923 extraction and leaching of low-grade pyrolusite using raffinate was proposed. After a two-stage countercurrent extraction, 99.93% Ti was extracted, while 6.51% Fe, .11% Mg, .06% Mn, and .08% Al were co-extracted under N1923 concentration of 25% and phase ratio (O/A) of 2/1. The scrubbing efficiency of iron reached 98.53%, while the loss efficiency of titanium was only .94% with 1.5 mol/L sulfuric acid solution under the phase ratio of 1/1. Then, the Ti-loaded organic phase could be effectively stripped by .8 mol/L ammonia water; the single-stage stripping efficiency of titanium was 99.23%. Subsequently, the raffinate could be used for the extraction of manganese from low-grade pyrolusite. The leaching efficiency of manganese was 99.39% at the S/L ratio of 48.00 g/L, leaching temperature of 50 degrees C, and leaching time of 40 min. In addition, thermodynamic calculations revealed that the titanium extraction process by N1923 from titanium white waste acid was an exothermic reaction. The proposed approach is suitable for co-recovery of titanium from titanium white waste acid and manganese from low-grade pyrolusite. |
| WOS关键词 | SULFURIC-ACID ; SOLVENT-EXTRACTION ; IRON OXIDATION ; MANGANESE ORES ; SEPARATION ; PRECIPITATION ; SCANDIUM ; VANADIUM ; MEDIA |
| 资助项目 | Major Science and Technology Program for Water Pollution Control and Treatment[2015ZX07205-003] ; China Ocean Mineral Resources Research and Development Association[JS-KTHT-2019-01] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000741306700001 |
| 出版者 | WILEY |
| 资助机构 | Major Science and Technology Program for Water Pollution Control and Treatment ; China Ocean Mineral Resources Research and Development Association |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51683]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Feng, Yali; Li, Haoran |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing, Peoples R China 2.Univ Sci & Technol Beijing, Civil & Resource Engn Sch, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ju, Jinrong,Feng, Yali,Li, Haoran. Recovery of Ti from titanium white waste acid with N1923 extraction and leaching of low-grade pyrolusite using raffinate[J]. ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,2022:12. |
| APA | Ju, Jinrong,Feng, Yali,&Li, Haoran.(2022).Recovery of Ti from titanium white waste acid with N1923 extraction and leaching of low-grade pyrolusite using raffinate.ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,12. |
| MLA | Ju, Jinrong,et al."Recovery of Ti from titanium white waste acid with N1923 extraction and leaching of low-grade pyrolusite using raffinate".ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING (2022):12. |
入库方式： OAI收割
来源：过程工程研究所
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