中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag

文献类型:期刊论文

作者Ju, Jinrong1,2,3; Feng, Yali1; Li, Haoran2,3; Xu, Chenglong1; Yang, Yi1
刊名MINING METALLURGY & EXPLORATION
出版日期2022-01-22
页码16
关键词Steel slag Sulfuric acid leaching Solvent extraction Selective stripping Oxalic acid precipitation
ISSN号2524-3462
DOI10.1007/s42461-022-00552-w
英文摘要The dumping of a large amount of steel slag not only wastes metal resources, but pollutes the ecological environment. In this study, a method for recovery of vanadium, titanium, iron, magnesium, and synthesizing anhydrite from steel slag is proposed. The leaching efficiency of V, Ti, Fe, and Mg was 99.42%, 99.36%, 99.89%, and 99.95%, respectively, under a H2SO4 concentration of 30%, a leaching temperature of 70 degrees C, and a leaching time of 90 min. At the same time, anhydrite with a purity of 93.09% was obtained. The leachate can be reused twice, and the obtained gypsum was calcined at 200celcius to obtain anhydrite. 99.45% V and 99.98% Ti were extracted in leachate by two-stage countercurrent extraction with 25% P507 at an equilibrium pH of 1.6. 99.86% of the Fe in the raffinate can be recovered by the precipitation method. Subsequently, the 0.45 mol/L H2C2O4 was used to precipitate Mg as MgC2O4 center dot 2H(2)O under the pH value of 5.5, indicating that the precipitation efficiency of Mg can reach 98.39%. The present process can effectively separate vanadium, titanium, iron, and magnesium and synthesize anhydrite products realizing the cleaner utilization of steel slag.
WOS关键词SOLVENT-EXTRACTION ; LEACHING KINETICS ; CONVERTER SLAG ; WASTE-WATER ; CHROMIUM ; TRANSFORMATION ; AGGREGATE ; CONCRETE ; SULFATE
资助项目China Ocean Mineral Resources RD Association[JS-KTHT-2019-01] ; Major Science and Technology Program for Water Pollution Control and Treatment[2015ZX07205-003] ; National Natural Science Foundation of China[21176242] ; National Natural Science Foundation of China[21176026]
WOS研究方向Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing
语种英语
WOS记录号WOS:000745595300001
出版者SPRINGER HEIDELBERG
资助机构China Ocean Mineral Resources RD Association ; Major Science and Technology Program for Water Pollution Control and Treatment ; National Natural Science Foundation of China
源URL[http://ir.ipe.ac.cn/handle/122111/51764]  
专题中国科学院过程工程研究所
通讯作者Feng, Yali; Li, Haoran
作者单位1.Univ Sci & Technol Beijing, Civil & Resource Engn Sch, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Biochem Engn, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ju, Jinrong,Feng, Yali,Li, Haoran,et al. Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag[J]. MINING METALLURGY & EXPLORATION,2022:16.
APA Ju, Jinrong,Feng, Yali,Li, Haoran,Xu, Chenglong,&Yang, Yi.(2022).Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag.MINING METALLURGY & EXPLORATION,16.
MLA Ju, Jinrong,et al."Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag".MINING METALLURGY & EXPLORATION (2022):16.

入库方式: OAI收割

来源:过程工程研究所

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