Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag
文献类型:期刊论文
作者 | Ju, Jinrong1,2,3; Feng, Yali1; Li, Haoran2,3; Xu, Chenglong1; Yang, Yi1 |
刊名 | MINING METALLURGY & EXPLORATION
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出版日期 | 2022-01-22 |
页码 | 16 |
关键词 | Steel slag Sulfuric acid leaching Solvent extraction Selective stripping Oxalic acid precipitation |
ISSN号 | 2524-3462 |
DOI | 10.1007/s42461-022-00552-w |
英文摘要 | The dumping of a large amount of steel slag not only wastes metal resources, but pollutes the ecological environment. In this study, a method for recovery of vanadium, titanium, iron, magnesium, and synthesizing anhydrite from steel slag is proposed. The leaching efficiency of V, Ti, Fe, and Mg was 99.42%, 99.36%, 99.89%, and 99.95%, respectively, under a H2SO4 concentration of 30%, a leaching temperature of 70 degrees C, and a leaching time of 90 min. At the same time, anhydrite with a purity of 93.09% was obtained. The leachate can be reused twice, and the obtained gypsum was calcined at 200celcius to obtain anhydrite. 99.45% V and 99.98% Ti were extracted in leachate by two-stage countercurrent extraction with 25% P507 at an equilibrium pH of 1.6. 99.86% of the Fe in the raffinate can be recovered by the precipitation method. Subsequently, the 0.45 mol/L H2C2O4 was used to precipitate Mg as MgC2O4 center dot 2H(2)O under the pH value of 5.5, indicating that the precipitation efficiency of Mg can reach 98.39%. The present process can effectively separate vanadium, titanium, iron, and magnesium and synthesize anhydrite products realizing the cleaner utilization of steel slag. |
WOS关键词 | SOLVENT-EXTRACTION ; LEACHING KINETICS ; CONVERTER SLAG ; WASTE-WATER ; CHROMIUM ; TRANSFORMATION ; AGGREGATE ; CONCRETE ; SULFATE |
资助项目 | China Ocean Mineral Resources RD Association[JS-KTHT-2019-01] ; Major Science and Technology Program for Water Pollution Control and Treatment[2015ZX07205-003] ; National Natural Science Foundation of China[21176242] ; National Natural Science Foundation of China[21176026] |
WOS研究方向 | Metallurgy & Metallurgical Engineering ; Mining & Mineral Processing |
语种 | 英语 |
WOS记录号 | WOS:000745595300001 |
出版者 | SPRINGER HEIDELBERG |
资助机构 | China Ocean Mineral Resources RD Association ; Major Science and Technology Program for Water Pollution Control and Treatment ; National Natural Science Foundation of China |
源URL | [http://ir.ipe.ac.cn/handle/122111/51764] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Feng, Yali; Li, Haoran |
作者单位 | 1.Univ Sci & Technol Beijing, Civil & Resource Engn Sch, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ju, Jinrong,Feng, Yali,Li, Haoran,et al. Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag[J]. MINING METALLURGY & EXPLORATION,2022:16. |
APA | Ju, Jinrong,Feng, Yali,Li, Haoran,Xu, Chenglong,&Yang, Yi.(2022).Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag.MINING METALLURGY & EXPLORATION,16. |
MLA | Ju, Jinrong,et al."Efficient Separation and Recovery of Vanadium, Titanium, Iron, Magnesium, and Synthesizing Anhydrite from Steel Slag".MINING METALLURGY & EXPLORATION (2022):16. |
入库方式: OAI收割
来源:过程工程研究所
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