Ru single atoms induce surface-mediated discharge in Na-O(2 )batteries
文献类型：期刊论文
| 作者 | Jin, Xin1; Li, Yangyang1; Zhang, Shuo1; Zhang, Jiangwei2,3; Shen, Zihan1; Zhong, Chenlin1; Cai, Ziqiang1; Hu, Chaoquan4,5; Zhang, Huigang1,4 |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2022 |
| 卷号 | 33期号:1页码:491-496 |
| ISSN号 | 1001-8417 |
| 关键词 | Na-O-2 batteries Ru single atoms Surface-mediated mechanism Adsorption energy Co-deposition |
| DOI | 10.1016/j.cclet.2021.06.090 |
| 英文摘要 | Sodium (Na) O-2 batteries have high energy density and low cost. However, high polarization, complex discharge products, and low Coulombic efficiency (CE) lead to poor cyclability. Here, we proposed an atomically dispersed Ru catalyst on nitrogen-doped graphene for Na-O-2 batteries. The catalysts enable the discharge to proceed via a surface-mediated route, which leads to uniform deposition of Na2-xO2 and low polarization during recharge. The first-principle calculation revealed that Ru-N-4 complex in the catalyst has strong chemical adsorption to intermediate superoxides, facilitating uniform deposition and enhancing rapid kinetics. In contrast, Ru nanoparticles, despite the catalytic activity, induce bulk deposition via a solution-mediated route because the exposed graphene surface shows weak interaction to superoxides, thereby lowering CEs and cyclability. In brief, the atomically-dispersed Ru catalyst endows Na-O-2 batteries with excellent electrochemical properties via a surface-mediated discharge. (C) 2021 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. |
| WOS关键词 | SODIUM SUPEROXIDE ; HIGHLY EFFICIENT ; BATTERIES ; METAL ; NAO2 ; REDUCTION ; CHEMISTRY ; TRANSPORT ; CATHODES ; GROWTH |
| 资助项目 | National Natural Science Foundation of China[22075131] ; National Natural Science Foundation of China[21776121] ; National Key R&D Program of China[2020YFA0406104] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE INC |
| WOS记录号 | WOS:000746501400079 |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D Program of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51814]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Huigang |
| 作者单位 | 1.Nanjing Univ, Coll Engn & Appl Sci, Collaborat Innovat Ctr Adv Microstruct, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 5.Nanjing IPE Inst Green Mfg Ind, Nanjing 211100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Xin,Li, Yangyang,Zhang, Shuo,et al. Ru single atoms induce surface-mediated discharge in Na-O(2 )batteries[J]. CHINESE CHEMICAL LETTERS,2022,33(1):491-496. |
| APA | Jin, Xin.,Li, Yangyang.,Zhang, Shuo.,Zhang, Jiangwei.,Shen, Zihan.,...&Zhang, Huigang.(2022).Ru single atoms induce surface-mediated discharge in Na-O(2 )batteries.CHINESE CHEMICAL LETTERS,33(1),491-496. |
| MLA | Jin, Xin,et al."Ru single atoms induce surface-mediated discharge in Na-O(2 )batteries".CHINESE CHEMICAL LETTERS 33.1(2022):491-496. |
入库方式： OAI收割
来源：过程工程研究所
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