In Situ Carbon Encapsulation Confined Nickel-Doped Indium Oxide Nanocrystals for Boosting CO2 Electroreduction to the Industrial Level
文献类型：期刊论文
| 作者 | Chen, Zhipeng1,2; Yu, Guang2; Li, Bin2; Zhang, Xinxin2; Jiao, Mingyang2; Wang, Nailiang3; Zhang, Xiangping4; Liu, Licheng2 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2021-12-03 |
| 卷号 | 11期号:23页码:14596-14604 |
| 关键词 | CO2 electroreduction nickel doping carbon encapsulation electronic structure nanocrystals |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.1c04182 |
| 英文摘要 | The reaction current density for the CO2 electroreduction to formate of indium-based catalysts cannot meet the needs of industrial applications. Herein, the nickel-doped indium oxide nanocrystals (similar to 7 nm) confined in carbon nanofibers (Ni-In2O3@C NFs) demonstrate a formate partial current density of over 350 mA cm(-2) at a moderate overpotential of 0.8 V, and particularly, the formate Faradaic efficiency (FE) is above 90% in a wide potential region from -0.6 to -1.0 V. More remarkably, a long-term stability of 55 h with an industrially relevant current density of similar to 200 mA cm(-2) can be achieved after improving hydrophobicity of gas diffusion electrodes (GDEs). Experimental results combined with DFT calculations confirm that the enhanced activity is attributed to the synergistic effect of nickel doping and carbon encapsulation in engineering the electronic structure of In2O3 nanocrystals, which enhances the adsorption strength of OCHO* intermediates and accelerates the charge transfer rate. |
| WOS关键词 | ELECTROCATALYTIC REDUCTION ; ELECTROCHEMICAL REDUCTION ; CURRENT-DENSITY ; HIGH-EFFICIENCY ; DIOXIDE ; ELECTRODES ; CATALYSTS ; DEFECT ; NANOPARTICLES ; SELECTIVITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000753063400029 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/51942]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Licheng |
| 作者单位 | 1.Anhui Univ Technol, Sch Chem & Chem Engn, Maanshan 243032, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Shandong, Peoples R China 3.Ningxia Univ, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Zhipeng,Yu, Guang,Li, Bin,et al. In Situ Carbon Encapsulation Confined Nickel-Doped Indium Oxide Nanocrystals for Boosting CO2 Electroreduction to the Industrial Level[J]. ACS CATALYSIS,2021,11(23):14596-14604. |
| APA | Chen, Zhipeng.,Yu, Guang.,Li, Bin.,Zhang, Xinxin.,Jiao, Mingyang.,...&Liu, Licheng.(2021).In Situ Carbon Encapsulation Confined Nickel-Doped Indium Oxide Nanocrystals for Boosting CO2 Electroreduction to the Industrial Level.ACS CATALYSIS,11(23),14596-14604. |
| MLA | Chen, Zhipeng,et al."In Situ Carbon Encapsulation Confined Nickel-Doped Indium Oxide Nanocrystals for Boosting CO2 Electroreduction to the Industrial Level".ACS CATALYSIS 11.23(2021):14596-14604. |
入库方式： OAI收割
来源：过程工程研究所
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