Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon
文献类型:期刊论文
作者 | Li, Ying-xia1; Hou, Shao-xing1,2; Wei, Quan-yuan3,4; Ma, Xiao-shan1,2; Qu, Yong-Shui2 |
刊名 | ACS OMEGA
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出版日期 | 2021-12-21 |
卷号 | 6期号:50页码:34386-34394 |
ISSN号 | 2470-1343 |
DOI | 10.1021/acsomega.1c04318 |
英文摘要 | In the process of lignin extraction by the organic solvent method, the amount of alkali and the content of 1,4butanediol are important conditions that affect lignin yield. The effects of alkali and alcohol contents on lignin recovery, removal rate, and structure were studied. In this reaction system, the removal rate of lignin increased with the increase of alkali content but decreased with the increase of alcohol content. Fourier transform infrared (FT-IR) analysis showed that the phenol hydroxyl group and the ether bond in lignin had different trends in different alkali and 1,4-butanediol environments, and four different infrared parameters in lignin had an obvious linear relationship. Gel permeation chromatography (GPC) results showed that high alkali content and high 1,4-butanediol content could lead to the fragmentation of lignin. In addition, lignin extracted from alkali-quantity factor series was selected to prepare activated carbon, CaCl2 was selected as the activator, and its effects were studied. Results showed that in the process of extracting lignin, on the one hand, NaOH content affects the functional groups of activated carbon by affecting the aromatic structure of lignin; on the other hand, the NaOH content affects the graphitization degree and specific surface area of activated carbon by affecting the removal rate and the molecular weight of lignin. |
WOS关键词 | SURFACE-AREA ; TEMPERATURE ; ADSORPTION ; STONES |
资助项目 | National Science and Technology Major Project of the Ministry of Science and Technology of China[2018ZX07105-004] ; National Natural Science Foundation of China[2170060476] ; Beijing Science and Technology Plan[Z181100002418019] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000757429500019 |
出版者 | AMER CHEMICAL SOC |
资助机构 | National Science and Technology Major Project of the Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Science and Technology Plan |
源URL | [http://ir.ipe.ac.cn/handle/122111/51986] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Qu, Yong-Shui |
作者单位 | 1.Beijing Univ Chem Technol, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 3.Beijing Zhong Yuan Chuang Neng Engn & Technol Ltd, Beijing 100101, Peoples R China 4.Beijing Int Cooperat Base Sci Tec Innovat Organ W, Beijing 100101, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Ying-xia,Hou, Shao-xing,Wei, Quan-yuan,et al. Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon[J]. ACS OMEGA,2021,6(50):34386-34394. |
APA | Li, Ying-xia,Hou, Shao-xing,Wei, Quan-yuan,Ma, Xiao-shan,&Qu, Yong-Shui.(2021).Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon.ACS OMEGA,6(50),34386-34394. |
MLA | Li, Ying-xia,et al."Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon".ACS OMEGA 6.50(2021):34386-34394. |
入库方式: OAI收割
来源:过程工程研究所
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