中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon

文献类型:期刊论文

作者Li, Ying-xia1; Hou, Shao-xing1,2; Wei, Quan-yuan3,4; Ma, Xiao-shan1,2; Qu, Yong-Shui2
刊名ACS OMEGA
出版日期2021-12-21
卷号6期号:50页码:34386-34394
ISSN号2470-1343
DOI10.1021/acsomega.1c04318
英文摘要In the process of lignin extraction by the organic solvent method, the amount of alkali and the content of 1,4butanediol are important conditions that affect lignin yield. The effects of alkali and alcohol contents on lignin recovery, removal rate, and structure were studied. In this reaction system, the removal rate of lignin increased with the increase of alkali content but decreased with the increase of alcohol content. Fourier transform infrared (FT-IR) analysis showed that the phenol hydroxyl group and the ether bond in lignin had different trends in different alkali and 1,4-butanediol environments, and four different infrared parameters in lignin had an obvious linear relationship. Gel permeation chromatography (GPC) results showed that high alkali content and high 1,4-butanediol content could lead to the fragmentation of lignin. In addition, lignin extracted from alkali-quantity factor series was selected to prepare activated carbon, CaCl2 was selected as the activator, and its effects were studied. Results showed that in the process of extracting lignin, on the one hand, NaOH content affects the functional groups of activated carbon by affecting the aromatic structure of lignin; on the other hand, the NaOH content affects the graphitization degree and specific surface area of activated carbon by affecting the removal rate and the molecular weight of lignin.
WOS关键词SURFACE-AREA ; TEMPERATURE ; ADSORPTION ; STONES
资助项目National Science and Technology Major Project of the Ministry of Science and Technology of China[2018ZX07105-004] ; National Natural Science Foundation of China[2170060476] ; Beijing Science and Technology Plan[Z181100002418019]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000757429500019
出版者AMER CHEMICAL SOC
资助机构National Science and Technology Major Project of the Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Beijing Science and Technology Plan
源URL[http://ir.ipe.ac.cn/handle/122111/51986]  
专题中国科学院过程工程研究所
通讯作者Qu, Yong-Shui
作者单位1.Beijing Univ Chem Technol, Beijing 100029, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China
3.Beijing Zhong Yuan Chuang Neng Engn & Technol Ltd, Beijing 100101, Peoples R China
4.Beijing Int Cooperat Base Sci Tec Innovat Organ W, Beijing 100101, Peoples R China
推荐引用方式
GB/T 7714
Li, Ying-xia,Hou, Shao-xing,Wei, Quan-yuan,et al. Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon[J]. ACS OMEGA,2021,6(50):34386-34394.
APA Li, Ying-xia,Hou, Shao-xing,Wei, Quan-yuan,Ma, Xiao-shan,&Qu, Yong-Shui.(2021).Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon.ACS OMEGA,6(50),34386-34394.
MLA Li, Ying-xia,et al."Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon".ACS OMEGA 6.50(2021):34386-34394.

入库方式: OAI收割

来源:过程工程研究所

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