Ionic liquid surfactant-derived carbon micro/nanostructures toward application of supercapacitors
文献类型：期刊论文
| 作者 | Li, Weizheng1; Gao, Qiang1; Shen, Ming1; Li, Bingyu1; Ren, Chuanli2; Yang, Jun3 |
| 刊名 | INORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2022-02-14 |
| 页码 | 13 |
| ISSN号 | 2052-1553 |
| DOI | 10.1039/d1qi01570b |
| 英文摘要 | N-Doped mesoporous hollow carbon spheres (MHCSs) with different inner structures have attracted increasing attention in energy storage devices due to their low density and high electrical conductivity. Herein, vesicles formed by the molecular self-assembly of the ionic liquid surfactant derived from its unique properties (e.g. lower charge density and pi-pi interaction between the polar heads) are employed as soft templates to synthesize two kinds of uniform MHCSs (e.g. mesoporous hollow carbon spheres and core-shell structured carbon nanospheres) with high nitrogen (N) doping and various inner layouts including hollow, yolk-shell and Momordica grosvenori-like structures. The elaborate tailoring in the architectures of full sized MHCSs (55 nm-2 mu m) endows them with welcome features as electrode materials for symmetrical supercapacitors. In particular, the representative sample of as-prepared N-doped MHCSs exhibits excellent electric double-layer capacitor performance with an electrochemical specific capacitance (308 F g(-1) at 0.2 A g(-1)), superb capacitance retentions (233 F g(-1) at 20 A g(-1) and 174 F g(-1) at 100 A g(-1)), and high cycling stability (85% capacitance retention at 10 A g(-1) after 5000 cycles) in a 6 M KOH electrolyte. The full-sized carbon spheres with tunable architectures are expected to find more applications in catalysis, adsorption, biomedicine and energy storage and conversion devices. |
| WOS关键词 | PERFORMANCE ; NANOSPHERES ; SPHERES ; FABRICATION ; ELECTRODE ; VESICLES ; POLYMER |
| 资助项目 | Natural Science Foundation of China[21673201] ; Natural Science Foundation of China[22075290] ; Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP) ; Priority Academic Program Development of Jiangsu Higher Education Institutions |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000760412900001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Natural Science Foundation of China ; Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP) ; Priority Academic Program Development of Jiangsu Higher Education Institutions |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/52071]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Shen, Ming |
| 作者单位 | 1.Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China 2.Yangzhou Univ, Clin Med Coll, Yangzhou 225001, Jiangsu, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Weizheng,Gao, Qiang,Shen, Ming,et al. Ionic liquid surfactant-derived carbon micro/nanostructures toward application of supercapacitors[J]. INORGANIC CHEMISTRY FRONTIERS,2022:13. |
| APA | Li, Weizheng,Gao, Qiang,Shen, Ming,Li, Bingyu,Ren, Chuanli,&Yang, Jun.(2022).Ionic liquid surfactant-derived carbon micro/nanostructures toward application of supercapacitors.INORGANIC CHEMISTRY FRONTIERS,13. |
| MLA | Li, Weizheng,et al."Ionic liquid surfactant-derived carbon micro/nanostructures toward application of supercapacitors".INORGANIC CHEMISTRY FRONTIERS (2022):13. |
入库方式： OAI收割
来源：过程工程研究所
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