Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes
文献类型：期刊论文
| 作者 | Jin, Xin1,7,8; Cai, Ziqiang7,8; Zhang, Xinrui1,2; Yu, Jianming7,8; He, Qiya1,3; Lu, Zhenda7,8; Dahbi, Mouad6; Alami, Jones6; Lu, Jun4; Amine, Khalil4,5 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2022-03-20 |
| 页码 | 11 |
| ISSN号 | 0935-9648 |
| 关键词 | Li-metal anodes liquid metals solid electrolyte transfer technology wettability |
| DOI | 10.1002/adma.202200181 |
| 英文摘要 | Integrating solid-state electrolyte (SSE) into Li-metal anodes has demonstrated great promise to unleash the high energy density of rechargeable Li-metal batteries. However, fabricating a highly cyclable SSE/Li-metal anode remains a major challenge because the densification of the SSE is usually incompatible with the reactive Li metal. Here, a liquid-metal-derived hybrid solid electrolyte (HSE) is proposed, and a facile transfer technology to construct an artificial HSE on the Li metal is reported. By tuning the wettability of the transfer substrates, electron- and ion-conductive liquid metal is sandwiched between electron-insulating and ion-conductive LiF and oxides to form the HSE. The transfer technology renders the HSE continuous, dense, and uniform. The HSE, having high ion transport, electron shut-off, and mechanical strength, makes the composite anode deliver excellent cyclability for over 4000 h at 0.5 mA cm(-2) and 1 mAh cm(-2) in a symmetrical cell. When pairing with LiFePO4 and sulfur cathodes, the HSE-coated Li metal dramatically enhances the performance of full cells. Therefore, this work demonstrates that tuning the interfacial wetting properties provides an alternate approach to build a robust solid electrolyte, which enables highly efficient Li-metal anodes. |
| WOS关键词 | HIGH-ENERGY ; INTERPHASE ; BATTERY ; CONDUCTIVITY ; NUCLEATION ; DEPOSITION ; NITROGEN ; GROWTH |
| 资助项目 | National Key Research and Development Program of China[2020YFA0406104] ; National Natural Science Foundation of China[22075131] ; State Key Laboratory of Multiphase Complex Systems[MPCS-2021-A] ; Clean Vehicles, US-China Clean Energy Research Centre (CERC-CVC2) under US DOE EERE Vehicle Technologies Office ; DOE[DE-AC02-06CH11357] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000770840400001 |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; State Key Laboratory of Multiphase Complex Systems ; Clean Vehicles, US-China Clean Energy Research Centre (CERC-CVC2) under US DOE EERE Vehicle Technologies Office ; DOE |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/52437]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Lu, Jun; Amine, Khalil; Zhang, Huigang |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China 3.Northwest Univ, Sch Chem Engn, Shaanxi R&D Ctr Biomat & Fermentat Engn, Shaanxi Key Lab Degradable Biomed Mat, Taibai North Rd 229, Xian 710069, Shaanxi, Peoples R China 4.Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA 5.Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA 6.Mohammed VI Polytech Univ, Mat Sci & Nanoengn Dept, Ben Guerir, Morocco 7.Nanjing Univ, Natl Lab Solid State Microstruct, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China 8.Nanjing Univ, Coll Engn & Appl Sci, Nanjing 210093, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Xin,Cai, Ziqiang,Zhang, Xinrui,et al. Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes[J]. ADVANCED MATERIALS,2022:11. |
| APA | Jin, Xin.,Cai, Ziqiang.,Zhang, Xinrui.,Yu, Jianming.,He, Qiya.,...&Zhang, Huigang.(2022).Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes.ADVANCED MATERIALS,11. |
| MLA | Jin, Xin,et al."Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes".ADVANCED MATERIALS (2022):11. |
入库方式： OAI收割
来源：过程工程研究所
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