Open-Framework Metal Oxides for Fast and Reversible Hydrated Zinc-Ion Intercalation
文献类型：期刊论文
| 作者 | Yang, Hailun1,2; Ning, Pengge1,2; Chen, Junwu1,2; Li, Yuping1,2; He, Hongyan1,2; Cao, Hongbin1,2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2022-03-02 |
| 卷号 | 14期号:8页码:10407-10418 |
| 关键词 | aqueous zinc-ion batteries expanded vanadium oxide hydrated zinc-ion intercalation binder-free electrode flexible quasi-solid state |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.1c23995 |
| 英文摘要 | The development of high capacity and stable cathodes is the key to the successful commercialization of aqueous zinc-ion batteries. However, significant solvation penalties limit the choice of available positive electrodes. Herein, hydrated intercalation is proposed to promote reversible (de)intercalation within host materials by rationally designing a matching electrode. In contrast to previously reported works, the as-prepared electrode (NHVO@CC) can achieve fast and reversible intercalation of hydrated zinc ions in the interlayer gap, leading to a high capacity of 517 mAh g(-1) at 0.1 A g(-1) and excellent electrode stability for long-term cycling. Besides, as a consequence of the flexibility of the NHVO@CC electrode, a quasi-solid-state battery was achieved with equally advantageous electrochemical behavior under various bending states. The proposed hydrated cation direct insertion/extraction sets up an efficient way of developing high-performance positive electrodes for aqueous batteries. |
| WOS关键词 | HIGH-CAPACITY ; ENERGY-STORAGE ; CATHODE ; BATTERY ; INSERTION ; ELECTRODE ; VANADATE ; RAMAN ; HETEROSTRUCTURES ; NANOSHEETS |
| 资助项目 | National Natural Science Foundation of China[51934006] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000778608900040 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/52491]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Ning, Pengge; Cao, Hongbin |
| 作者单位 | 1.Chinese Acad Sci, Natl Key Lab Biochem Engn, CAS Key Lab Green Proc & Engn,Innovat Acad Green, Inst Proc Engn,Beijing Engn Res Ctr Proc Pollut C, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Hailun,Ning, Pengge,Chen, Junwu,et al. Open-Framework Metal Oxides for Fast and Reversible Hydrated Zinc-Ion Intercalation[J]. ACS APPLIED MATERIALS & INTERFACES,2022,14(8):10407-10418. |
| APA | Yang, Hailun,Ning, Pengge,Chen, Junwu,Li, Yuping,He, Hongyan,&Cao, Hongbin.(2022).Open-Framework Metal Oxides for Fast and Reversible Hydrated Zinc-Ion Intercalation.ACS APPLIED MATERIALS & INTERFACES,14(8),10407-10418. |
| MLA | Yang, Hailun,et al."Open-Framework Metal Oxides for Fast and Reversible Hydrated Zinc-Ion Intercalation".ACS APPLIED MATERIALS & INTERFACES 14.8(2022):10407-10418. |
入库方式： OAI收割
来源：过程工程研究所
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