Accurately Localizing Multiple Nanoparticles in a Multishelled Matrix Through Shell-to-Core Evolution for Maximizing Energy-Storage Capability
文献类型：期刊论文
| 作者 | Li, Bo1,2; Wang, Jiangyan1,3; Bi, Ruyi1; Yang, Nailiang1,3; Wan, Jiawei1,3; Jiang, Hongyu4; Gu, Lin4; Du, Jiang5,6; Cao, Anmin7,8; Gao, Wei2 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2022-04-03 |
| 页码 | 8 |
| ISSN号 | 0935-9648 |
| 关键词 | cycling stability hollow multishelled structures lithium-ion batteries shell-to-core evolution Sn anodes |
| DOI | 10.1002/adma.202200206 |
| 英文摘要 | Robust and fast lithium energy storage with a high energy density is highly desired to accelerate the market adoption of electric vehicles. To realize such a goal requires the development of electrode materials with a high capacity, however, such electrode materials suffer from huge volume expansion and induced short cycling life. Here, using tin (Sn) as an example, an ideal structure is designed to effectively solve these problems by separately localizing multiple Sn nanoparticles in a nitrogen-doped carbon hollow multishelled structure with duplicated layers for carbon shell (Sn NPs@NxC HoMS-DL). The fabricated composite can promote ion and electron diffusion owing to the conductive network formed by connected multiple shells and cores, effectively buffer the volume expansion, and maintain a stable electrode-electrolyte interface. Despite the challenging fabrication, such a structure is realized through an innovative and facile synthesis strategy of "in situ evolution of shell to core", which is applicable for diverse low-melting-point materials. As expected, such a structure enables the high-capacity electrode material to realize nearly its theoretical lithium-storage capability: the developed Sn NPs@NxC HoMS-DL electrode maintains 96% of its theoretical capacity after 2000 cycles at 2C. |
| WOS关键词 | HOLLOW MICROSPHERES ; THERMAL-DEGRADATION ; ANODE MATERIALS ; PERFORMANCE ; CARBON ; SN ; POLYDOPAMINE ; NANOCRYSTALS ; EXPANSION ; CO3O4 |
| 资助项目 | National Natural Science Foundation of China[21820102002] ; National Natural Science Foundation of China[21931012] ; National Natural Science Foundation of China[21971244] ; National Natural Science Foundation of China[52022097] ; National Natural Science Foundation of China[2202055] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000777647100001 |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/52528]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Dan |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, 1 North 2nd St, Beijing 100190, Peoples R China 2.Univ Auckland, Fac Engn, Dept Chem & Mat Engn, Auckland 92019, New Zealand 3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 10049, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China 5.Zhengzhou Univ, Sch Mat Sci & Engn, Green Catalysis Ctr, Zhengzhou 450001, Peoples R China 6.Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China 7.Chinese Acad Sci, Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100190, Peoples R China 8.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Bo,Wang, Jiangyan,Bi, Ruyi,et al. Accurately Localizing Multiple Nanoparticles in a Multishelled Matrix Through Shell-to-Core Evolution for Maximizing Energy-Storage Capability[J]. ADVANCED MATERIALS,2022:8. |
| APA | Li, Bo.,Wang, Jiangyan.,Bi, Ruyi.,Yang, Nailiang.,Wan, Jiawei.,...&Wang, Dan.(2022).Accurately Localizing Multiple Nanoparticles in a Multishelled Matrix Through Shell-to-Core Evolution for Maximizing Energy-Storage Capability.ADVANCED MATERIALS,8. |
| MLA | Li, Bo,et al."Accurately Localizing Multiple Nanoparticles in a Multishelled Matrix Through Shell-to-Core Evolution for Maximizing Energy-Storage Capability".ADVANCED MATERIALS (2022):8. |
入库方式： OAI收割
来源：过程工程研究所
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