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Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose

文献类型：期刊论文

作者Peng, Fubin2,3,4; Sun, Ying4; Hua, Chao1,5,6; Bai, Fang1,5,6; Ma, Hong4; Hu, Xiangping4; Liu, Xin4,7; Zhang, Meiyun4,7; Wang, Xinhong2,3
刊名CHEMISTRYSELECT
出版日期2022-04-05
卷号7期号:13页码:8
关键词CuAlMoO4 CuAgAlMoO4 epimerization glucose mannose
ISSN号2365-6549
DOI10.1002/slct.202103224
英文摘要Molybdenum-based catalysts have been widely studied in the epimerization of glucose to mannose. In this paper, several polymetallic molybdenum-based catalysts were prepared and the high activity and selectivity of catalysts containing different divalent metal ions were investigated. Unlike most previous studies, there is no need to add acid to adjust pH in this reaction. It was found that the yield of CuAlMoO4 and CuAgAlMoO4 catalysts could be kept above 28.9 % at the epimerization of glucose reaction. Compared with soluble Cu3Mo2O9 catalysts, the prepared catalysts showed better stability and catalytic activity during the reaction process. It was found that the catalysts without copper had no catalytic effect or poor catalytic effect, and the valence state of copper ion changed before and after the reaction, indicating that copper ion played a very important role in the reaction.
WOS关键词MOLYBDATE IONS ; PHOTOLUMINESCENCE PROPERTIES ; SELECTIVE DEHYDRATION ; D-FRUCTOSE ; ISOMERIZATION ; EFFICIENT ; ACID ; ALDOSES ; SITES ; CU
资助项目Innovation Academy for Green Manufacture, Chinese Academy of Sciences[IAGM2020C08] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21030400] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDB17020300]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000777721700001
出版者WILEY-V C H VERLAG GMBH
资助机构Innovation Academy for Green Manufacture, Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences
源URL[http://ir.ipe.ac.cn/handle/122111/52618]  
专题中国科学院过程工程研究所
通讯作者Sun, Ying; Hua, Chao; Wang, Xinhong
作者单位1.Univ Chinese Acad Sci, Sch Chem & Engn, Beijing 100049, Peoples R China
2.Dalian Polytech Univ, Sch Text, Dalian 116034, Peoples R China
3.Dalian Polytech Univ, Mat Engn Inst, Dalian 116034, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
5.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China
6.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
7.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Peng, Fubin,Sun, Ying,Hua, Chao,et al. Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose[J]. CHEMISTRYSELECT,2022,7(13):8.
APA Peng, Fubin.,Sun, Ying.,Hua, Chao.,Bai, Fang.,Ma, Hong.,...&Wang, Xinhong.(2022).Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose.CHEMISTRYSELECT,7(13),8.
MLA Peng, Fubin,et al."Polymetallic Molybdenum-Based Catalysts for Epimerization of Glucose to Mannose".CHEMISTRYSELECT 7.13(2022):8.

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来源：过程工程研究所

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