PEO-based CO2-philic mixed matrix membranes compromising N-rich ultramicroporous polyaminals for superior CO2 capture
文献类型：期刊论文
| 作者 | Zhang, Xiaoxia1; Rong, Meng2,4; Qin, Peiyong1; Tan, Tianwei1,3 |
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2022-02-15 |
| 卷号 | 644页码:13 |
| 关键词 | CO2-Philic mixed matrix membrane PEO membrane Polyaminal Polymer molecular sieve CO2 capture |
| ISSN号 | 0376-7388 |
| DOI | 10.1016/j.memsci.2021.120111 |
| 英文摘要 | Polymer molecular sieve materials (PMS) are promising porous fillers that can be used to fabricate highperformance gas separation mixed matrix membranes (MMMs) to overcome the inherent trade-off. In this work, a nitrogen-rich ultramicroporous (0.34 nm, 0.50 nm) polyaminal network (PAN-NH2) was introduced into crosslinked PEO polymer to prepare CO2-philic MMMs with superior CO2 capture performance. Due to the synergistical interaction of the dipole-quadrupole and molecular sieving effect, PAN-NH2 demonstrates excellent molecular recognition of CO2. PAN-NH2 can be well dispersed in polymer matrix to achieve good polymer-filler interface compatibility. The incorporation of PAN-NH2 significantly improves the CO2 permeability and selectivity of membranes by increasing the CO2 solubility and providing a selective CO2 transport highway. For instance, the CO2 permeability of mixed gas (15% CO2/85% N-2, 50% CO2/50% CH4) permeation tests for 2.0 wt % PAN-NH2/PEO was increased from 340 Barrer (crosslinked PEO) to 1160 Barrer along with CO2/N-2 selectivity of 73.0 and CO2/CH4 selectivity of 19.7, surpassing the Upper bound (2019) and Upper bound (2008), respectively. The long-time stability of PAN-NH2/PEO MMMs is good, which endow them with great potential in practical CO2 capture. In addition, this work demonstrates the potential of functional ultramicroporous PMS in the preparation of high-performance MMMs for other gas separation processes. |
| WOS关键词 | COVALENT ORGANIC FRAMEWORK ; POLY(ETHYLENE OXIDE) ; PERMEATION PROPERTIES ; CO2/N-2 SEPARATIONS ; GAS-PERMEATION ; CARBON-DIOXIDE ; POLYMERS ; PERFORMANCE ; DESIGN ; PERMEABILITY |
| 资助项目 | National Key Research and Development Program of China[2019YFB1503904] ; National Natural Science Foundation of China[21861132017] ; National Natural Science Foundation of China[22108281] ; China Postdoctoral Science Foundation[2021M703239] |
| WOS研究方向 | Engineering ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000788533500005 |
| 出版者 | ELSEVIER |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/52998]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Rong, Meng; Tan, Tianwei |
| 作者单位 | 1.Beijing Univ Chem Technol, Coll Life Sci & Technol, Beijing Key Lab Bioproc, 10029, Beijing, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 3.Beijing Univ Chem Technol, Coll Life Sci & Technol, Beijing Key Lab Bioproc, North Third Rd 15 Chaoyang Dist, Beijing 100029, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, 1 North 2nd St,Zhongguancun,Haidian Dist, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Zhang, Xiaoxia,Rong, Meng,Qin, Peiyong,et al. PEO-based CO2-philic mixed matrix membranes compromising N-rich ultramicroporous polyaminals for superior CO2 capture [J]. JOURNAL OF MEMBRANE SCIENCE,2022,644:13. |
| APA |
Zhang, Xiaoxia,Rong, Meng,Qin, Peiyong,&Tan, Tianwei.(2022). PEO-based CO2-philic mixed matrix membranes compromising N-rich ultramicroporous polyaminals for superior CO2 capture .JOURNAL OF MEMBRANE SCIENCE,644,13. |
| MLA |
Zhang, Xiaoxia,et al." PEO-based CO2-philic mixed matrix membranes compromising N-rich ultramicroporous polyaminals for superior CO2 capture ".JOURNAL OF MEMBRANE SCIENCE 644(2022):13. |
入库方式： OAI收割
来源：过程工程研究所
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