Activated carbon adsorption coupled with ozonation regeneration for efficient removal of chlorobenzene
文献类型：期刊论文
| 作者 | Ren, Mingzhu1,2; Wang, Jing2; Wang, Zhengyang3; Sun, Sihan2; Qiu, Jiakai2; Shi, Yanchun2; Wang, Zhou-jun1; Xie, Yongbing2 |
| 刊名 | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
 |
| 出版日期 | 2022-04-01 |
| 卷号 | 10期号:2页码:10 |
| ISSN号 | 2213-2929 |
| 关键词 | Chlorobenzene Adsorption Quantum chemical calculation Reaction mechanism Ozonation regeneration |
| DOI | 10.1016/j.jece.2022.107319 |
| 英文摘要 | Chlorobenzene is a typical toxic and persistent organic pollutant in wastewater and site polluted groundwater. In this study, powdered activated carbon (AC) was used for the adsorption of chlorobenzene from simulated wastewater, and it showed high adsorption capacity in a wide range of pH. Pseudo-second-order kinetic model and Langmuir isothermal adsorption model are suitable to describe the adsorption process. Furthermore, the adsorption mechanism is clarified by correlating the adsorption rate constants with the molecular descriptor by theory calculating. Chlorobenzene adsorption on AC was mainly controlled by pi-pi interaction and hydrophobicity, external mass transfer and intraparticle diffusion. Ozonation was adopted to regenerate the adsorption saturated AC and simultaneously avoid secondary solid waste. After three cycles of adsorption-ozonation, the adsorption capacity of AC even increased from 80 to 215 mg/g due to the increase of oxygen-containing func-tional groups on the AC surface. This mode can also be used for granular AC column adsorption, and ozonation partially restored the adsorption capacity. The work provides a better alternative way to deal with chlorobenzene polluted wastewater and groundwater. |
| WOS关键词 | AROMATIC-COMPOUNDS ; AQUEOUS-SOLUTION ; ENERGY RELATIONSHIPS ; PHARMACEUTICALS ; PREDICTION ; KINETICS |
| 资助项目 | National key research and development program[2018YFC1801501] ; Tianjin Municipal Science and Technology Bureau[18YFYSZ00170] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000788084000006 |
| 资助机构 | National key research and development program ; Tianjin Municipal Science and Technology Bureau |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/53162]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Wang, Zhou-jun; Xie, Yongbing |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Energy Environm Catalysis, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Beijing Engn Res Ctr Proc Pollut Control, Inst Proc Engn, Div Environm Engn & Technol, Beijing 100190, Peoples R China 3.Connecticut Agr Expt Stn, Dept Environm Sci, New Haven, CT 06504 USA |
| 推荐引用方式 GB/T 7714 | Ren, Mingzhu,Wang, Jing,Wang, Zhengyang,et al. Activated carbon adsorption coupled with ozonation regeneration for efficient removal of chlorobenzene[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2022,10(2):10. |
| APA | Ren, Mingzhu.,Wang, Jing.,Wang, Zhengyang.,Sun, Sihan.,Qiu, Jiakai.,...&Xie, Yongbing.(2022).Activated carbon adsorption coupled with ozonation regeneration for efficient removal of chlorobenzene.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,10(2),10. |
| MLA | Ren, Mingzhu,et al."Activated carbon adsorption coupled with ozonation regeneration for efficient removal of chlorobenzene".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 10.2(2022):10. |
入库方式： OAI收割
来源：过程工程研究所
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