Strained carbocycle based hypergolic ionic fuels with the improved energy capacity
文献类型：期刊论文
| 作者 | Jiao, Nianming1; Yuan, Yanyan2; Yao, Yuan3; Liu, Long1; Zhang, Yanqiang1,3 |
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2022-06-15 |
| 卷号 | 231页码:9 |
| 关键词 | Hypergolic ionic liquid Propellant Ring strain Energy Density |
| ISSN号 | 0378-3820 |
| DOI | 10.1016/j.fuproc.2022.107248 |
| 英文摘要 | Different from the previous nitrogenous groups, we present a new strategy of improving the ionic liquids (ILs) energy capacity by introducing the strained carbocycles. The ILs with three-and/or four-member carbocycles were prepared, and their physicochemical properties as rocket fuels were studied. The ignition tests show that all of these ILs have the expected hypergolic reactivity with the oxidizer (white fuming HNO3). In virtue of the strained cyclopropane and cyclobutane substituents, the resulting hypergolic ILs possess better energy properties (heats of formation 0.784-1.968 kJ g(-1); specific impulses 313.0-315.7 s) and densities (1.03-1.15 g cm(-3)) than the corresponding ILs with n-alkyl substituents. This strategy of introducing strained ring groups into hypergolic ILs gives a new approach to improve energy properties of hypergolic ILs. |
| WOS关键词 | BASIS-SETS ; AB-INITIO ; LIQUIDS ; VALENCE ; DENSITY ; CHARGE ; ATOMS |
| 资助项目 | National Natural Science Foundation of China[21878278] ; National Natural Science Foundation of China[22008245] ; National Natural Science Foundation of China[U21A20307] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000791148500004 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/53180]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Long; Zhang, Yanqiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Sci & Technol Particle Mat, Beijing 100190, Peoples R China 2.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Peoples R China 3.Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiao, Nianming,Yuan, Yanyan,Yao, Yuan,et al. Strained carbocycle based hypergolic ionic fuels with the improved energy capacity[J]. FUEL PROCESSING TECHNOLOGY,2022,231:9. |
| APA | Jiao, Nianming,Yuan, Yanyan,Yao, Yuan,Liu, Long,&Zhang, Yanqiang.(2022).Strained carbocycle based hypergolic ionic fuels with the improved energy capacity.FUEL PROCESSING TECHNOLOGY,231,9. |
| MLA | Jiao, Nianming,et al."Strained carbocycle based hypergolic ionic fuels with the improved energy capacity".FUEL PROCESSING TECHNOLOGY 231(2022):9. |
入库方式： OAI收割
来源：过程工程研究所
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