MEIFUITE, A NEW FERROUS PHYLLOSILICATE MINERAL WITH MODULATED TETRAHEDRAL SHEETS SIMILAR TO MINNESOTAITE
文献类型：期刊论文
| 作者 | Jin, Shiyun1; Li, Xiaochun2,4; Hobbs, Franklin1; Guggenheim, Stephen3; Xu, Huifang1 |
| 刊名 | CLAYS AND CLAY MINERALS
 |
| 出版日期 | 2021-09-21 |
| 页码 | 16 |
| 关键词 | Fe-silicate mineral Meifuite Single-crystal XRD Strip modulated layer structure |
| ISSN号 | 0009-8604 |
| DOI | 10.1007/s42860-021-00143-8 |
| 英文摘要 | A new ferrous phyllosilicate, meifuite, has been discovered in the Yinachang Fe-Cu-REE (rare-earth element) deposit in China. The structural formula, calculated using averaged electron probe microanalysis ( EPMA) results, is K0.72Na0.20(Fe5.56Mg0.31Mn0.13)(Sigma 6.00)(Si6.95Al1.04)(Sigma 7.99)O-18.84(OH)(4.84)Cl-1.33, with an ideal formula of KFe6(AlSi7)O-19(OH)(4)Cl-2. The structure of meifuite has a P1 space group symmetry, with unit-cell parameters of a = 22.7773(13) angstrom, b = 9.5553(5) angstrom, c =14.3282(8) angstrom, alpha = 99.258(4)degrees, beta = 136.750(3)degrees, gamma = 89.899(4)degrees, Z = 2, and V = 2077.9(2) angstrom(3). Meifuite has a strip-modulated 2:1 layer (T-O-T) structure similar to that of minnesotaite. About 1/8 of the tetrahedra in the T sheet are occupied by Al instead of Si, and the interlayer cavities are partially occupied by K and Na. Some of the OH sites in the octahedral sheet in the layer structure are fully or partially substituted by Cl, which is apparently the primary reason for the meifuite structure being more stable than stilpnomelane, the most common ferrous layer silicate mineral found at similar temperature and pressure conditions. An updated, more accurate structure model of minnesotaite is also provided for comparison with the meifuite structure. The mineral is named after Meifu Zhou in honor of his outstanding contributions to the field of economic geology. |
| WOS关键词 | CRYSTAL-STRUCTURE ; IRON-RICH ; STILPNOMELANE ; DISORDER ; SYSTEM ; SILICATES |
| 资助项目 | Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; National Science Foundation[EAR-1530614] ; National Natural Science Foundation of China (NSFC)[17306814] |
| WOS研究方向 | Chemistry ; Geology ; Mineralogy ; Agriculture |
| 语种 | 英语 |
| WOS记录号 | WOS:000698109400001 |
| 出版者 | SPRINGER |
| 资助机构 | Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; National Science Foundation ; National Science Foundation ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; National Science Foundation ; National Science Foundation ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; National Science Foundation ; National Science Foundation ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; Bailey Fellowship of the Department of Geoscience of the University of Wisconsin-Madison ; National Science Foundation ; National Science Foundation ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) |
| 源URL | [http://ir.iggcas.ac.cn/handle/132A11/102675]  |
| 专题 | 地质与地球物理研究所_中国科学院矿产资源研究重点实验室 |
| 通讯作者 | Xu, Huifang |
| 作者单位 | 1.Univ Wisconsin, Dept Geosci, SW Bailey Xray Diffract Lab, Madison, WI 53706 USA 2.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China 3.Univ Illinois, Dept Earth & Environm Sci, Chicago, IL 60607 USA 4.Univ Chinese Acad Sci, Coll Earth & Planetary Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Shiyun,Li, Xiaochun,Hobbs, Franklin,et al. MEIFUITE, A NEW FERROUS PHYLLOSILICATE MINERAL WITH MODULATED TETRAHEDRAL SHEETS SIMILAR TO MINNESOTAITE[J]. CLAYS AND CLAY MINERALS,2021:16. |
| APA | Jin, Shiyun,Li, Xiaochun,Hobbs, Franklin,Guggenheim, Stephen,&Xu, Huifang.(2021).MEIFUITE, A NEW FERROUS PHYLLOSILICATE MINERAL WITH MODULATED TETRAHEDRAL SHEETS SIMILAR TO MINNESOTAITE.CLAYS AND CLAY MINERALS,16. |
| MLA | Jin, Shiyun,et al."MEIFUITE, A NEW FERROUS PHYLLOSILICATE MINERAL WITH MODULATED TETRAHEDRAL SHEETS SIMILAR TO MINNESOTAITE".CLAYS AND CLAY MINERALS (2021):16. |
入库方式： OAI收割
来源：地质与地球物理研究所
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