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An Overlooked Natural Hydrogen Evolution Pathway: Ni2+ Boosting H2O Reduction by Fe(OH)(2) Oxidation during Low-Temperature Serpentinization

文献类型：期刊论文

作者Song, Han1,3; Ou, Xinwen3; Han, Bin3; Deng, Haoyu1,2; Zhang, Wenchao1,2; Tian, Chen1,2; Cai, Chunfang4; Lu, Anhuai5; Lin, Zhang1,2,3; Chai, Liyuan1,2
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2021-11-02
卷号60期号:45页码:24054-24058
关键词Fe(OH)(2) oxidation hydrogen production low-temperature serpentinization nickel water reduction
ISSN号1433-7851
DOI10.1002/anie.202110653
英文摘要Natural hydrogen (H-2) has gained considerable attentions as a renewable energy resource to mitigate the globally increasing environmental concerns. Low-temperature serpentinization (<200 degrees C) as a typical water-rock reaction is a major source of the natural H-2. However, the reaction mechanism and the controlling step to product H-2 remained unclear, which hinders the further utilization of natural H-2. Herein, we demonstrated that the H-2 production rate could be determined by the Fe(OH)(2) oxidation during low-temperature serpentinization. Moreover, the co-existence of Ni2+ could largely enhance the H-2 production kinetics. With the addition of only 1 % Ni2+, the H-2 production rate was remarkably enhanced by about two orders of magnitude at 90 degrees C. D2O isotopic experiment and theoretical calculations revealed that the enhanced H-2 production kinetics could be attributed to the catalytic role of Ni2+ to promote the reduction of H2O.
WOS关键词H-2 ; MAGNETITE
资助项目National Natural Science Foundation of China[21836002] ; National Key Research and Development Program of China[2019YFA0210403] ; Guangdong Innovative and Entrepreneurial Research Team Program[2016ZT06N569]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000710630000021
出版者WILEY-V C H VERLAG GMBH
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Guangdong Innovative and Entrepreneurial Research Team Program ; Guangdong Innovative and Entrepreneurial Research Team Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Guangdong Innovative and Entrepreneurial Research Team Program ; Guangdong Innovative and Entrepreneurial Research Team Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Guangdong Innovative and Entrepreneurial Research Team Program ; Guangdong Innovative and Entrepreneurial Research Team Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Guangdong Innovative and Entrepreneurial Research Team Program ; Guangdong Innovative and Entrepreneurial Research Team Program
源URL[http://ir.iggcas.ac.cn/handle/132A11/103847]  
专题地质与地球物理研究所_中国科学院新生代地质与环境重点实验室
通讯作者Lin, Zhang
作者单位1.Cent South Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China
2.Chinese Natl Engn Res Ctr Control & Treatment Hea, Changsha 410083, Hunan, Peoples R China
3.South China Univ Technol, Sch Environm & Energy, Guangdong Prov Key Lab Solid Wastes Pollut Contro, Guangzhou 510006, Guangdong, Peoples R China
4.Chinese Acad Sci, Key Lab Cenozo Geol & Environm, Inst Geol & Geophys, Beijing 100029, Peoples R China
5.Peking Univ, Sch Earth & Space Sci, Beijing Key Lab Mineral Environm Funct, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714		 Song, Han,Ou, Xinwen,Han, Bin,et al. An Overlooked Natural Hydrogen Evolution Pathway: Ni2+ Boosting H2O Reduction by Fe(OH)(2) Oxidation during Low-Temperature Serpentinization[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021,60(45):24054-24058.
APA Song, Han.,Ou, Xinwen.,Han, Bin.,Deng, Haoyu.,Zhang, Wenchao.,...&Chai, Liyuan.(2021).An Overlooked Natural Hydrogen Evolution Pathway: Ni2+ Boosting H2O Reduction by Fe(OH)(2) Oxidation during Low-Temperature Serpentinization.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,60(45),24054-24058.
MLA Song, Han,et al."An Overlooked Natural Hydrogen Evolution Pathway: Ni2+ Boosting H2O Reduction by Fe(OH)(2) Oxidation during Low-Temperature Serpentinization".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 60.45(2021):24054-24058.

入库方式： OAI收割

来源：地质与地球物理研究所

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